ChemicalBook Product Catalog Chemical Reagents Organic reagents Esters Methyl ester compound Methyl 1-cyclohexene-1-carboxylate

Methyl 1-cyclohexene-1-carboxylate

Methyl 1-cyclohexene-1-carboxylate Basic information
Product Name:Methyl 1-cyclohexene-1-carboxylate
Synonyms:1-Cyclohexene-1-carboxylic acid, methyl ester;METHYL 3,4,5,6-TETRAHYDROBENZOATE;METHYL 1-CYCLOHEXENE-1-CARBOXYLATE;METHYL 1-CYCLOHEXENECARBOXYLATE;METHYL CYCLOHEXENE-1-CARBOXYLATE;CYCLOHEXENE-1-CARBOXYLIC ACID METHYL ESTER;CYCLOHEX-1-ENECARBOXYLIC ACID METHYL ESTER;RARECHEM AL BF 0805
CAS:18448-47-0
MF:C8H12O2
MW:140.18
EINECS:242-331-5
Product Categories:C8 to C9;Carbonyl Compounds;Esters;Building Blocks;C8 to C9;Carbonyl Compounds;heterocyclic/Aliphatic series;Aromatic Esters;Chemical Synthesis;Organic Building Blocks
Mol File:18448-47-0.mol
Methyl 1-cyclohexene-1-carboxylate Structure
Methyl 1-cyclohexene-1-carboxylate Chemical Properties
Boiling point 190-192 °C
density 1.028 g/mL at 20 °C(lit.)
refractive index n20/D 1.477
Fp 165 °F
storage temp. Sealed in dry,Room Temperature
form Liquid
color Clear colorless
Water Solubility insoluble
BRN 1071971
CAS DataBase Reference18448-47-0(CAS DataBase Reference)
NIST Chemistry ReferenceMethyl 1-cyclohexene-1-carboxylate(18448-47-0)
Safety Information
Safety Statements 23-24/25
WGK Germany 3
F 10-23
HS Code 29162090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Methyl 1-cyclohexene-1-carboxylate Usage And Synthesis
Chemical Propertiesclear colorless liquid
UsesMethyl 1-cyclohexene-1-carboxylate is used in the diastereoselective synthesis of cis-1,2-dialkenylcyclopropanols and methyl -7,7-dimethyl-9-oxo-1,3,4,4a,6,7,8,9,9b-decahydrodibenzo[b,d]furan-4a-carboxylate.
Synthesis Reference(s)The Journal of Organic Chemistry, 33, p. 1550, 1968 DOI: 10.1021/jo01268a053
Tetrahedron Letters, 17, p. 453, 1976
Methyl 1-cyclohexene-1-carboxylate Preparation Products And Raw materials
Preparation Products3-METHOXYCYCLOHEXENE-->Cyclohexanecarboxylic acid, 2-(aminomethyl)-, methyl ester-->Cyclohexanecarboxylic acid, 2-methyl-, (1S,2R)-
Triptonide Methyl METHYL PERILLATE Triptolide 4-METHYLCYCLOHEXENE-1,2-DIMETHANOIC ANHYDRIDE RARECHEM AQ BC 9125 HYPOLIDE METHYL ETHER Bensulfuron methyl 14-EPITRIPTOLIDE Methyl-2-methyl-1-cyclohexene-1-carboxylate TRIPTOPHENOLIDE SEDANOLIDE Kresoxim-methyl METHYL 2-AMINO-1-CYCLOHEXENE-1-CARBOXYLATE Thiophanate-methyl 3-Cyclohexen-1-yl-methyl-3-cyclohexene-1-carboxylate METSULFURON METHYL METHYL 3-CYCLOHEXENE-1-CARBOXYLATE
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