Ethylene dimethacrylate

Ethylene dimethacrylate Basic information
Description Referrence
Product Name:Ethylene dimethacrylate
Synonyms:Ethylene glycol diMethacrylate, 90 to 110 ppM MEHQ as stabilizer;2-methyl-2-propenoicacid,1,2-ethanediylester;2-Propenoicacid,2-methyl-,1,2-ethanediylester;GLYCOL HEMA-METHACRYLATE;Ageflex egdm;Ageflex EGDMA;ageflexegdm;Diglycol dimethacrylate
CAS:97-90-5
MF:C10H14O4
MW:198.22
EINECS:202-617-2
Product Categories:Functional Monomer;bc0001
Mol File:97-90-5.mol
Ethylene dimethacrylate Structure
Ethylene dimethacrylate Chemical Properties
Melting point -40 °C
Boiling point 98-100 °C/5 mmHg (lit.)
density 1.051 g/mL at 25 °C (lit.)
vapor density >1 (vs air)
vapor pressure <0.1 mm Hg ( 21.1 °C)
refractive index n20/D 1.454(lit.)
Fp >230 °F
storage temp. Store below +30°C.
solubility <5g/l
form Liquid
color Colorless to pale yellow
Water Solubility soluble
BRN 1776663
Stability:Unstable - may polymerize upon exposure to light. Incompatible with strong acids, strong oxidizing agents, strong bases.
LogP2.4 at 20℃
CAS DataBase Reference97-90-5(CAS DataBase Reference)
NIST Chemistry Reference2-Propenoic acid, 2-methyl-, 1,2-ethanediyl ester(97-90-5)
EPA Substance Registry SystemEthylene glycol dimethacrylate (97-90-5)
Safety Information
Hazard Codes Xi
Risk Statements 37-43
Safety Statements 24-37-36/37
RIDADR UN 3334
WGK Germany 1
RTECS OZ4400000
8-19
TSCA Yes
HS Code 29161490
Hazardous Substances Data97-90-5(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 3300 mg/kg
MSDS Information
ProviderLanguage
Ethylene glycol dimethacrylate English
SigmaAldrich English
ACROS English
ALFA English
Ethylene dimethacrylate Usage And Synthesis
DescriptionIt is mainly applied in the field of organic synthesis, such as a crosslinking agent for fabricating resin, resin processing, fabricating adhesives and coatings, rubber resin modifier, anaerobic adhesive, and plastic paste. Specifically, this chemical can be used as the raw material to prepare a copolymer that has been demonstrated to act as a biocompatible interface between glucose biosensors and tissue in the rat.1 Moreover, this compound may be involved in the preparation of poly(2-vinyl-4,4-dimethylazlactone-co-acrylamide-co-ethylene dimethacrylate) for designing the porous support for high throughput reactors.2 In addition, the bulk polymerization of this chemical and glycidyl methacrylate results in the formation of porous monolith as a stationary phase in dye-affinity chromatography.3
Referrence
  1. Quinn, C. P.; Pathak, C. P.; Heller, A.; Hubbell, J. A., PHOTO-CROSS-LINKED COPOLYMERS OF 2-HYDROXYETHYL METHACRYLATE, POLY(ETHYLENE GLYCOL) TETRA-ACRYLATE AND ETHYLENE DIMETHACRYLATE FOR IMPROVING BIOCOMPATIBILITY OF BIOSENSORS. Biomaterials 1995, 16, 389-396.
  2. Xie, S. F.; Svec, F.; Frechet, J. M. J., Design of reactive porous polymer supports for high throughput bioreactors: Poly(2-vinyl-4,4-dimethylazlactone-co-acrylamide-co-ethyl dimethacrylate) monoliths. Biotechnol. Bioeng. 1999, 62, 30-35.
  3. Uzun, L.; Yavuz, H.; Say, R.; Ersoz, A.; Denizli, A., Poly(ethylene dimethacrylate-glycidyl methacrylate) monolith as a stationary phase in dye-affinity chromatography. Ind. Eng. Chem. Res. 2004, 43, 6507-6513.
DescriptionThe crosslinking agent of acrylic resins, ethyleneglycol dimethacrylate (EGDMA), is employed to optimize the dilution of high-viscosity monomers and to link together the macromolecules costituting the polymer. It caused contact dermatitis in dental technicians and dental assistants. A case was also reported in a car rear-view mirror manufacturer.
Chemical Propertiescolourless liquid
UsesIt is used as a monomer to prepare Hydroxyapatite/Poly methyl methacrylate composites. 1
EGDMA can be used in free radical copolymer crosslinking reactions.
UsesEthylene glycol dimethacrylate is used as a functional monomer for polymers and as a cross linking agent between the molecular chains of polymers and elastomers. It is also used in free radical copolymer cross linking reactions. It acts as an intermediate in the production of hydroxyapatite and poly methyl methacrylate composites.
UsesEthylene glycol dimethacrylate is a cross-linking methacrylic monomer in dentaI composites, sealants, prostheses, adhesives, artificiaI nails, printing inks, etc.
DefinitionChEBI: The enoate ester that is the 1,2-bis(methacryloyl) derivative of ethylene glycol.
General DescriptionEthylene glycol dimethylacrylate (EGDMA) is a diester formed by condensation of two equivalents of methacrylic acid and one equivalent of ethylene glycol.
Flammability and ExplosibilityNonflammable
Ethylene dimethacrylate Preparation Products And Raw materials
Raw materialsMethacrylic acid
ETHYLENE GLYCOL MONOSTEARATE Ethyl ring acid ETHYLENE GLYCOL DISTEARATE 2-METHOXYETHYL VINYL ETHER ACETIC ACID 2-PHENOXYETHYL ESTER tiglic acid Poly(glycidyl methacrylate-co-ethylene dimethacrylate) POLY(ETHYLENE GLYCOL) ACRYLATE Hydroxypropyl acrylate POLY(ETHYLENE GLYCOL) (N) MONOMETHACRYLATE PHENYL METHACRYLATE PROPYLENE GLYCOL Dodecyl 2-methylacrylate 1,2-PROPANEDIOL DIMETHACRYLATE 1,4-Butanediol dimethacrylate Oil agent 403 1H,1H,5H-OCTAFLUOROPENTYL METHACRYLATE tetradecyl methacrylate Glycol Dimethacrylate

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