5-NITROACENAPHTHENE

5-NITROACENAPHTHENE Basic information
Product Name:5-NITROACENAPHTHENE
Synonyms:5-NITROACENAPHTHENE;Nitroacenaphthene;1,2-dihydro-5-nitro-acenaphthylen;1,2-dihydro-5-nitroacenaphthylene;1,2-Dihydro-5-nitro-acenaphthylene;5-Nan;5-Nitro-1,2-dihydroacenaphthylene;5-nitro-acenaphthen
CAS:602-87-9
MF:C12H9NO2
MW:199.21
EINECS:210-025-0
Product Categories:Intermediates of Dyes and Pigments;Aromatic Compounds
Mol File:602-87-9.mol
5-NITROACENAPHTHENE Structure
5-NITROACENAPHTHENE Chemical Properties
Melting point 100-101 °C(lit.)
Boiling point 279°C
density 1.1919 (rough estimate)
refractive index 1.5880 (estimate)
Fp 279°C
storage temp. -20°C Freezer
solubility Chloroform (Slightly), DMSO (Slightly)
form Solid
color Light Yellow to Yellow
BRN 1876864
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference602-87-9(CAS DataBase Reference)
IARC2B (Vol. 16, Sup 7) 1987
EPA Substance Registry System5-Nitroacenaphthene (602-87-9)
Safety Information
Hazard Codes T,Xi
Risk Statements 45
Safety Statements 53-45
RIDADR 2811
WGK Germany 3
RTECS AB1060000
Hazard Note Irritant
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29049090
Hazardous Substances Data602-87-9(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
5-NITROACENAPHTHENE Usage And Synthesis
Chemical Propertiesyellow powder
Chemical Properties5-Nitroacenaphthene is a yellow crystalline solid.
Uses5-Nitroacenaphthene is a derivative of acenaphthene, a polycyclic hydrocarbon that has potential to act as polyploidizing agents in plants.
DefinitionChEBI: 5-Nitroacenaphthene is a nitronaphthalene.
General DescriptionYellow powder.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileAromatic nitro compounds, such as 5-NITROACENAPHTHENE, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.
Health HazardACUTE/CHRONIC HAZARDS: There is clear evidence that 5-NITROACENAPHTHENE is an animal carcinogen. When heated to decomposition it emits toxic fumes of NOx.
Fire HazardFlash point data for 5-NITROACENAPHTHENE are not available. 5-NITROACENAPHTHENE is probably combustible.
Safety ProfileConfirmed carcinogen with experimental carcinogenic and neoplastigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS OF AROMATIC HYDROCARBONS.
Potential ExposureUsed in organic synthesis.
ShippingUN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
Incompatibilities5-Nitroacenaphthene is an aromatic hydrocarbon (nitro compound). It may be flammable or explosive. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides; alkalis may increases the thermal sensitivity of this chemical.
Waste DisposalCareful incineration in an incinerator equipped with afterburner and scrubbers.
5-NITROACENAPHTHENE Preparation Products And Raw materials
Raw materialsAcenaphthene
Preparation Products4-Nitro-1,8-Naphthalenedicarboxylic Acid-->4-Nitronaphthalene-1,8-dicarboxylic anhydride
Nitroguanidine Nitric acid 5-Amino-4-nitroacenaphthene,5-Amino-4-nitroacenaphthene 5-NITROACENAPHTHENE SOLUTION 100UG/ML IN METHANOL 5X1ML,5-NITROACENAPHTHENE SOLUTION 100UG/ML IN METHANOL 5X1ML 3-NITROACENAPHTHENE,3-NITROACENAPHTHENE ACENAPHTHYLENE 1-Acenaphthenol, 5-nitro- 5,6-DINITROACENAPHTHENE 5-NITROACENAPHTHENE SOLUTION 100UG/ML IN METHANOL 5ML,5-NITROACENAPHTHENE SOLUTION 100UG/ML IN METHANOL 5ML 5-NITROACENAPHTHENE-4,4'-DINITROBIPHENYL,5-NITROACENAPHTHENE-4,4'-DINITROBIPHENYL 5-NITROACENAPHTHENE (D9),5-NITROACENAPHTHENE (D9) 1-Acenaphthenone, 5-nitro- 5-NITROACENAPHTHENE (D9) SOLUTION 50UG/ML IN TOLUENE 1.2ML,5-NITROACENAPHTHENE (D9) SOLUTION 50UG/ML IN TOLUENE 1.2ML 5-ACETAMINO-4-NITROACENAPHTHENE,5-ACETAMINO-4-NITROACENAPHTHENE 5-NITROACENAPHTHENE SOLUTION 100UG/ML IN METHANOL 1ML,5-NITROACENAPHTHENE SOLUTION 100UG/ML IN METHANOL 1ML Acenaphthene 5-NITROACENAPHTHENE 6-Nitroacenaphthene-3-sulfonic acid sodium salt,6-Nitroacenaphthene-3-sulfonic acid sodium salt

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