1,4,7-TRITHIACYCLONONANE

1,4,7-TRITHIACYCLONONANE Basic information
Product Name:1,4,7-TRITHIACYCLONONANE
Synonyms:1,4,7-TRITHIACYCLONONANE;TRIETHYLENE TRISULFIDE;[9]aneS3;Hexahydro-1,4,7-trithionin;1,4,7-Trithiacyclononane,Triethylene trisulfide;1,4,7-Trithiacyclononane 97%;1,4,7-trithionane;1,4,7-TRITHIACYCLONONANE ISO 9001:2015 REACH
CAS:6573-11-1
MF:C6H12S3
MW:180.35
EINECS:
Product Categories:Crown Ethers;Functional Materials;Macrocycles for Host-Guest Chemistry
Mol File:6573-11-1.mol
1,4,7-TRITHIACYCLONONANE Structure
1,4,7-TRITHIACYCLONONANE Chemical Properties
Melting point 78-81 °C (lit.)
Boiling point 79-80 °C
density 1.140±0.06 g/cm3(Predicted)
BRN 1616445
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 2934.99.9001
MSDS Information
ProviderLanguage
SigmaAldrich English
1,4,7-TRITHIACYCLONONANE Usage And Synthesis
Uses1,4,7-Trithiacyclononane (9S3) is a tridentate thioether ligand that can be used to prepare complexes with a wide variety of transition metal ions. These complexes often possess exceptional electronic and redox properties. 9S3 ligand reacts with palladium metal ion to form palladium(II) thioether complex, which is used as a catalyst in the C-H activation reactions. Manganese complex of 9S3 ligand is employed as a catalyst for the oxidation of olefins, alkanes, and alcohols.
DefinitionChEBI: 1,4,7-trithionane is a crown thioether that is cyclononane in which the carbon atoms at positions 1, 4 and 7 are replaced by sulfur atoms. It is a tridentate thioether ligand that is used to synthesise complexes with a wide variety of transition metal ions. It has a role as a chelator. It is a saturated organic heteromonocyclic parent and a crown thioether.
1,4,7-TRITHIACYCLONONANE Preparation Products And Raw materials
Raw materials1,2-Dibromoethane
1,4,7,10,13,16-HEXATHIACYCLOOCTADECANE [12]Cycloparaphenylene 1,4,7,10-TETRATHIACYCLODODECANE trithiacyclononane 3,6-DITHIAOCTANE Bis(2-mercaptoethyl) sulfide 1,4,7-TRITHIACYCLONONANE

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