BARIUM THIOSULFATE

BARIUM THIOSULFATE Basic information
Product Name:BARIUM THIOSULFATE
Synonyms:thiosulfuricacid(h2s2o3),bariumsalt(1:1);BARIUM THIOSULFATE;Barium thiosulfate hydrate;barium thiosulphate;Bariumthiosulfatewhitepowder;Bariumthiosulfate,98%;Barium hyposulfite;Thiosulfuric acid barium salt
CAS:35112-53-9
MF:BaO3S2
MW:249.46
EINECS:252-375-7
Product Categories:Barium;Inorganic Salts;Synthetic Reagents
Mol File:35112-53-9.mol
BARIUM THIOSULFATE Structure
BARIUM THIOSULFATE Chemical Properties
Melting point decomposes at 220℃ [CRC10]
density 3.45
form white crystalline powder
Water Solubility insoluble EtOH; 0.220 g/100g H2O [CRC10]
Merck 13,1002
Solubility Product Constant (Ksp)pKsp: 4.79
Exposure limitsACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
CAS DataBase Reference35112-53-9(CAS DataBase Reference)
EPA Substance Registry SystemThiosulfuric acid (H2S2O3), barium salt (1:1) (35112-53-9)
Safety Information
Hazard Codes Xn
Risk Statements 20/22
Safety Statements 28
RIDADR UN 1564 6.1/PG 3
WGK Germany 1
TSCA Yes
HazardClass 6.1
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
BARIUM THIOSULFATE Usage And Synthesis
DescriptionBarium thiosulfate has the molecular formula of BaS2O3 and the molecular weight of 249.4602 g/mol. It can be prepared by the reaction of sodium thiosulfate in water with the chloride of barium:
BaCl2+Na2S2O3 ? BaS2O3+2NaCl
It is not very soluble in water (0.25 g/100 ml at 15°C) so that the solution does not need to be evaporated at a low temperature to crystallize the product. A monohydrate is the result. BaS2O3·H2O has the CAS number of 35112-53-9. It is insoluble in ethanol. It is a white, crystalline, water-insoluble, poisonous solid. It loses the water of hydration at 110°C and decomposes at 228°C to form the sulfate, sulfur and SO2.
BaS2O3·H2O is used chiefly in the manufacture of explosives, matches, paints, and varnishes. However,the demand for this chemical is not substantial and it is classified as a “rare” chemical.


Chemical PropertiesWhite, crystalline powder.Slightly soluble in water; insoluble in alcohol.
UsesBarium thiosulfate (BaS2O3) is mainly used in explosives, matches, varnishes, and photography.
UsesExplosives, luminous paints, matches, varnishes, photography.
Purification MethodsIt is very slightly soluble in water and is washed repeatedly with chilled water and dried in air at 40o.
BARIUM THIOSULFATE Preparation Products And Raw materials
SODIUM TETRATHIONATE DIHYDRATE Beryllium Thiosulfate Calcium Pyrosulfate Beryllium Pyrosulfate Radium Pyrosulfate STRONTIUM THIOSULFATE SILVER BROMIDE Potassium chromate CALCIUM THIOSULFATE Magnesium thiosulfate hexahydrate Radium Thiosulfate calcium bicarbonate BARIUM SULFIDE BARIUM THIOSULFATE H2O,BARIUM THIOSULFATE MONOHYDRATE BARIUM THIOSULFATE BARIUM SULFITE BARIUM HYDRIDE Barium sulfate

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