4-Isopropoxylphenylboronic acid

4-Isopropoxylphenylboronic acid Basic information
Product Name:4-Isopropoxylphenylboronic acid
Synonyms:4-ISOPROPOXYBENZENEBORONIC ACID;4-ISOPROPOXYLPHENYLBORONIC ACID;AKOS BRN-0675;CHEMBRDG-BB 4009733;P-ISOPROPOXYPHENYLBORONIC ACID;4-isopropyloxyphenyl-boronic acid;4-Isopropoxyphebylboronic acid;4-Isopropoxyphenylboronic
CAS:153624-46-5
MF:C9H13BO3
MW:180.01
EINECS:
Product Categories:Potassium Trifluoroborate;Boronate Ester;Aryl Boronic Acids;Boronic Acids and Derivatives;Chemical Synthesis;Monosubstituted Aryl Boronic Acids;Organometallic Reagents;Boronic Acid series;blocks;BoronicAcids;Boronic acid;Boronic Acids;Boronic Acids and Derivatives;Alkoxy;Aryl;Organoborons;Boronic acids
Mol File:153624-46-5.mol
4-Isopropoxylphenylboronic acid Structure
4-Isopropoxylphenylboronic acid Chemical Properties
Melting point 150-154°C
Boiling point 321.9±44.0 °C(Predicted)
density 1.10±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
pka8.78±0.17(Predicted)
form Powder
color White to off-white or light tan
CAS DataBase Reference153624-46-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39-36-24/25
WGK Germany 3
HazardClass IRRITANT
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
4-Isopropoxylphenylboronic acid Usage And Synthesis
Chemical PropertiesWhite to off-white or light tan powder
Uses4-Isopropoxyphenylboronic Acid is used to synthesize potent cytotoxic analogues of the marine alkaloid Lamellarin D. It is also used to synthesize cyclooxygenase-2 (COX-2) inhibitors.
Usessuzuki reaction
UsesReactant for:• ;Microwave-mediated click-chemistry synthesis of glyco-porphyrin derivatives with in vitro photo-cytotoxicity for application in photodynamic therapy1• ;Palladium-catalyzed oxidative cross-coupling reactions2• ;Ruthenium-catalyzed hydrogenation reactions3• ;Stereoselective rhodium-catalyzed arylation4• ;Palladium acetate catalyzed C-glycosidation5
General DescriptionContains varying amounts of anhydride
4-Isopropoxylphenylboronic acid Preparation Products And Raw materials
3-FLUORO-4-ISOPROPOXYPHENYLBORONIC ACID 2,2-DIMETHYL-3,4-DIHYDRO-2H-CHROMEN-6-YLBORONIC ACID 4-Methoxybenzyl cyanide 3,5-DIMETHYL-4-ISOPROPOXYPHENYLBORONIC & TERT-BUTYL 4-[4-(5,5-DIMETHYL-1,3,2-DIOXABORINAN-2-YL)PHENOXY]PIPERIDINE-1-CARBOXYLATE 4-ISOPROPOXY-2-METHYLPHENYLBORONIC ACID AKOS BRN-1115 4-CYCLOPENTOXYPHENYLBORONIC ACID 4-ISOPROPOXY-2-(TRIFLUOROMETHYL)PHENYLBORONIC ACID 4-ISOPROPOXY-3-METHYLPHENYLBORONIC ACID 2-CHLORO-4-ISOPROPROXYPHENYLBORONIC ACID 4-CYCLOPROPOXYPHENYLBORONIC ACID 4-T-BUTOXYPHENYLBORONIC ACID 4-ISOPROPOXY-3-(TRIFLUOROMETHYL)BENZENEBORONIC ACID 2,2-DIMETHYL-2,3-DIHYDRO-1-BENZOFURAN-5-YLBORONIC ACID TERT-BUTYL 3-[4-(5,5-DIMETHYL-1,3,2-DIOXABORINAN-2-YL)PHENOXY]PIPERIDINE-1-CARBOXYLATE 4-ISOPROPOXY-1,3-PHENYLENEBISBORONIC ACID 3-CHLORO-4-ISOPROPOXYPHENYLBORONIC ACID

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