Cerium fluoride

Cerium fluoride Basic information
Uses
Product Name:Cerium fluoride
Synonyms:Cerium fluoride (CeF3);Cerium fluorure;cerium(iii)fluorideanhydrous;ceriumfluoride(cef3);Cerium(III) fluoride trihydrate min;Cerium(III) fluoride, 99.9% (REO);Cerium(III) fluoride, anhydrous, REacton(R), 99.9% (REO);Cerium trifluoride (as fluorine)
CAS:7758-88-5
MF:CeF3
MW:197.1112096
EINECS:231-841-3
Product Categories:Inorganics;metal halide
Mol File:7758-88-5.mol
Cerium fluoride Structure
Cerium fluoride Chemical Properties
Melting point 1640 °C
Boiling point 2300 °C
density 6.16 g/mL at 25 °C(lit.)
Fp 2300°C
solubility Soluble in strong mineral acids.
form Powder
color white to off-white
Specific Gravity6.16
Water Solubility Practically insoluble in, but slowly hydrolyzed by water
Sensitive Hygroscopic
Merck 14,1998
Solubility Product Constant (Ksp)pKsp: 15.1
Exposure limitsACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
Stability:hygroscopic
CAS DataBase Reference7758-88-5(CAS DataBase Reference)
NIST Chemistry ReferenceCerium trifluoride(7758-88-5)
EPA Substance Registry SystemCerium fluoride (CeF3) (7758-88-5)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 22-24/25-37/39-26-36/37
WGK Germany 2
RTECS FK6125000
Hazard Note Irritant
TSCA Yes
HS Code 28461000
MSDS Information
ProviderLanguage
Cerium fluoride English
SigmaAldrich English
ACROS English
ALFA English
Cerium fluoride Usage And Synthesis
UsesCerium Fluoride, is the important raw material for polishing powder, special glass, metallurgical applications. In glass industry, it is considered to be the most efficient glass polishing agent for precision optical polishing. It is also used to decolorize glass by keeping iron in its ferrous state. In steel manufacturing, it is used to remove free Oxygen and Sulfur by forming stable oxysulfides and by tying up undesirable trace elements, such as lead and antimony.
Chemical PropertiesOff-white powder. Insoluble in water and acids.
UsesIn arc carbons to increase their brilliance; prepa- ration of cerium metal.
UsesCerium(III) fluoride is used to make Lewis acid. It is considered to be the most effective glass polishing agent for high precision optical polishing. Cerium fluoride used as a core additive to improve the properties of the eventual weld. The fluoride provides stability to the arc and also modifies the behavior of the molten metal flowing into the weld.
HazardAn irritant.
Flammability and ExplosibilityNonflammable
Safety ProfileLow toxicity by ingestion. See FLUORIDES and CERIUM COMPOUNDS. When heated to decomposition it emits toxic fumes of F-.
Cerium fluoride Preparation Products And Raw materials
Preparation ProductsCERIUM(IV) FLUORIDE
CERIUM(III) CHLORIDE Ammonium hydrogen difluoride Fluorine CERIUM (IV) FLUORIDE HYDRATE CERIUM Ammonium fluoride Boron trifluoride sodium fluoride Potassium fluoride TITANIUM(III) FLUORIDE Aluminum fluoride Sulfur hexafluoride Cerium fluoride FLUORIDE STANDARD Hydrogen fluoride CERIUM(IV) FLUORIDE Sodium fluoride CERIUM

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