5-Bromo-2-hydroxyacetophenone

5-Bromo-2-hydroxyacetophenone Basic information

Product Name:	5-Bromo-2-hydroxyacetophenone
Synonyms:	1-(5-BROMO-2-HYDROXYPHENYL)ETHANONE;2-ACETYL-4-BROMOPHENOL;5'-BROMO-2'-HYDROXYACETOPHENONE;5-BROMO-2-HYDROXYACETOPHENONE;1-(5-bromo-2-hydroxyphenyl)-ethanon;AKOS BBS-00006622;2’-hydroxy-5’-bromoacetophenone;5’-bromo-2’-hydroxy-acetophenon
CAS:	1450-75-5
MF:	C8H7BrO2
MW:	215.04
EINECS:	604-457-2
Product Categories:	Building Blocks;C7 to C8;C7 to C8;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Aromatic Acetophenones & Derivatives (substituted);Adehydes, Acetals & Ketones;Bromine Compounds;Phenols;Carbonyl Compounds;Ketones
Mol File:	1450-75-5.mol

5-Bromo-2-hydroxyacetophenone Chemical Properties

Melting point	58-61 °C(lit.)
Boiling point	135-143 °C(Press: 16 Torr)
density	1.586±0.06 g/cm3(Predicted)
storage temp.	Sealed in dry,Room Temperature
solubility	Soluble in Chloroform
pka	9.59±0.18(Predicted)
form	Solid
color	White to pale yellow
LogP	3.110 (est)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
WGK Germany	3
RTECS	KM5556350
HazardClass	IRRITANT
HS Code	29147000
Toxicity	mouse,LD50,intraperitoneal,> 1gm/kg (1000mg/kg),Indian Journal of Chemistry, Section B: Organic Chemistry, Including Medicinal Chemistry. Vol. 20, Pg. 480, 1981.

MSDS Information

Provider	Language
SigmaAldrich	English

5-Bromo-2-hydroxyacetophenone Usage And Synthesis

Chemical Properties	White to pale yellow crystalline powder
Uses	5?-Bromo-2?-hydroxyacetophenone (5-Bromo-2-hydroxyacetophenone) may be used in ligand in the preparation of tetrahedral metallocene complexes containing vanadium(IV), synthesis of {2?-[1-(5-bromo-2-oxidophenyl) ethylidene] benzohydrazidato (2-)} tris(pyridine) nickel(II)] pyridine solvate, synthesis of N?-[1-(5-bromo-2-hydroxyphenyl)ethylidene]-3,4,5-trihydroxybenzohydrazide dimethyl sulfoxide solvate trihydrate, preparation of 6-bromochromen-4-one.
Preparation	Preparation by Fries rearrangement of 4-bromophenyl acetate with aluminium chloride without solvent between 110° and 160° (84–91%).

5-Bromo-2-hydroxyacetophenone Preparation Products And Raw materials

Raw materials	Phenyl bromoacetate-->2-Hydroxy-5-broMoacetophenone oxiMe-->5-Bromo-2-methoxyacetophenone-->2-Bromo-2′-hydroxyacetophenone-->4-BROMOPHENOL ACETATE-->Ethyl acetate-->Acetyl chloride-->4-Bromophenol
Preparation Products	3',5'-Dibromo-2'-hydroxyacetophenone-->3'-BROMO-4'-HYDROXYACETOPHENONE-->5'-BROMO-2'-HYDROXY-3'-NITROACETOPHENONE-->1-(3-BROMO-2-HYDROXYPHENYL)ETHANONE-->6-BROMO-4-METHYL-3-PHENYLCOUMARIN

TIMTEC-BB SBB010036 1H-Inden-1-one,4-bromo-2,3-dihydro-7-hydroxy- 6-Bromo-2,3-dihydro-4H-chromen-4-one 5'-BROMO-2'-HYDROXY-4-METHOXYCHALCONE 6,8-DIBROMO-3-FORMYLCHROMONE, 99% 4-Bromo-6,7-dimethoxyindanone 6-BROMO-3-FORMYLCHROMONE 5'-BROMO-2'-HYDROXYPROPIOPHENONE 97 bis(5-bromo-2-hydroxyphenyl)ethanedione 6-BROMOFLAVONE 6-BROMO-3-CYANOCHROMONE 1-(5-BROMO-2-HYDROXY-4-METHOXYPHENYL)-ETHANONE 2-AMINO-6-BROMO-3-FORMYLCHROMONE 1-(5-BROMO-2-HYDROXYPHENYL)-3-PHENYLPROP-2-EN-1-ONE 5-BROMO-2-HYDROXYBENZOPHENONE 5-Bromo-2-hydroxyacetophenone 6-BROMOCHROMONE 2-AMINO-7-BROMO-5-OXO-5H-(1)BENZOPYRANO&

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