4,4'-Divinylbiphenyl

4,4'-Divinylbiphenyl Basic information
Product Name:4,4'-Divinylbiphenyl
Synonyms:4,4'-Divinylbiphenyl;4,4'-Diethenyl-1,1'-biphenyl;4,4-Divinyl-p-biphenyl;1,1'-Biphenyl,4,4'-diethenyl-;4,4'-Divinyl-1,1'-biphenyl
CAS:4433-13-0
MF:C16H14
MW:206.28
EINECS:
Product Categories:
Mol File:4433-13-0.mol
4,4'-Divinylbiphenyl Structure
4,4'-Divinylbiphenyl Chemical Properties
Melting point 153 °C(Solv: water (7732-18-5); ethanol (64-17-5))
Boiling point 341.6±22.0 °C(Predicted)
density 0.998±0.06 g/cm3(Predicted)
Safety Information
MSDS Information
4,4'-Divinylbiphenyl Usage And Synthesis
PreparationThe preparation of 4,4'-Divinylbiphenyl is as follows: Reaction flask (10 mL) equipped with stirring bar was charged with 4-vinylphenylboronic acid (135mg, 0.91 mmol), ethanol (96%) (2 mL), [{Pd(μ-OH)Cl(IPr)}2] (510-4 g, 4.55 × 10-7 mol). Reactionmixture was stirred at 22 C for 6 h. After completion of the reaction solvent was evaporated, theresidue was dissolved in hexane (5 mL) and extracted with water (2 × 2 mL). The organic layer wasdried over magnesium sulphate, and hexane was evaporated under reduced pressure. 176 mg of 4,4'-divinylbiphenyl was obtained as a white solid. Yield = 93%. 

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