5-Amino-2-bromopyridine

5-Amino-2-bromopyridine Basic information

Product Name:	5-Amino-2-bromopyridine
Synonyms:	2-Bromo-5-aminoyridine;TIMTEC-BB SBB005540;TIMTEC-BB SBB003823;LABOTEST-BB LT00129606;2-BROMO-5-AMINOPYRIDINE;5-BROMO-2-AMINOPYRIDINE;5-AMINO-2-BROMOPYRIDINE;3-AMINO-6-BROMOPYRIDINE
CAS:	13534-97-9
MF:	C5H5BrN2
MW:	173.01
EINECS:	628-541-3
Product Categories:	Building Blocks;C5;C5 to C6;Chemical Synthesis;Halogenated Heterocycles;Heterocyclic Building Blocks;Amino-pyridine series;C5Heterocyclic Building Blocks;Halogenated Heterocycles;Heterocyclic Building Blocks;Chemical Amines;Bromopyridines;Halopyridines;Aromatics;Boronic Acid;pharmacetical;Pyridine series;Amines;Bromides;Pyridine;pyridine derivative;Amines and Anilines;Heterocycles;pyridines;blocks
Mol File:	13534-97-9.mol

5-Amino-2-bromopyridine Chemical Properties

Melting point	75 °C
Boiling point	180 °C
density	1.6065 (rough estimate)
refractive index	1.5182 (estimate)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	soluble in Methanol
pka	1.87±0.10(Predicted)
form	Powder
color	Beige to brown-black
BRN	109102
CAS DataBase Reference	13534-97-9(CAS DataBase Reference)

Safety Information

Hazard Codes	Xn,Xi
Risk Statements	36/37/38
Safety Statements	26-36-37/39
RIDADR	UN 2811 6.1/PG 3
WGK Germany	3
F	10
HazardClass	IRRITANT
PackingGroup	III
HS Code	29333990

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

5-Amino-2-bromopyridine Usage And Synthesis

Chemical Properties	Light yellow needles
Uses	3-Amino-6-bromopyridine may undergo polymerization via Buchwald–Hartwig amination in the presence of sodium tert-butoxide and XPhos(2-dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl) ligand yielding para-linked and meta-linked polyaminopyridines.
General Description	3-Amino-6-bromopyridine can be synthesized via bromination of 3-aminopyridine using N-bromosuccinimide in acetonitrile.

5-Amino-2-bromopyridine Preparation Products And Raw materials

Raw materials	Hydrochloric acid-->Iron-->Stannous chloride dihydrate-->Phosphorus tribromide-->Phosphorus oxybromide-->Aluminium-nickel-->2-Hydroxy-5-nitropyridine-->2-Bromo-5-nitropyridine-->PHOSPHORUS PENTABROMIDE-->3-Amino-2-bromopyridine-->3-Aminopyridine-->2,6-Dibromopyridin-3-amine-->2-Amino-5-nitropyridine
Preparation Products	6-Bromoimidazo[1,2-a]pyridine-->ethyl 4,6-dichloro-1,5-naphthyridine-3-carboxylate-->2,2'-bipyridine-5,5'-diamine-->3-Amino-6-morpholinopyridine-->2-Bromo-5-iodopyridine

2,6-Dibromo-3-nitropyridine 2-Amino-5-bromopyridine-3-methanol 6-AMINO-3-BROMOPYRIDINE-2-CARBOXAMIDE ALTRENOGEST 2-bromopyridine 6-(DI-BOC-AMINO)-2-BROMOPYRIDINE 3-AMINO-5-BROMO-2-METHOXYPYRIDINE N1-(1-BROMO-4-NITRO-3-ISOQUINOLYL)BENZAMIDE 2-bromo-5-N-(dimethylamine)-pyridine Ethyl 2-amino-5-bromopyridine-3-carboxylate 3-BOCAMINO-4-BROMOPYRIDINE 4-BROMOPYRIDINE 2-N-(2-AMINOETHYL)-AMINO-5-BROMOPYRIDINE DIHYDROCHLORIDE AMINO ACIDS 6-BROMO-2-METHOXY-3-NITRO-PYRIDINE 2,3-DIBROMO-5-NITRO PYRIDINE N-(2,6-DIBROMOPYRIDIN-3-YL)-N-METHYLAMINE 4,6-DIBROMO-2-CHLOROPYRIDIN-3-AMINE

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