Bis(2-ethylhexyl) adipate

Bis(2-ethylhexyl) adipate Basic information
Product Name:Bis(2-ethylhexyl) adipate
Synonyms:vestinoloa;Wickenol 158;wickenol158;WITAMOL 320;witamol320;Witcizer 412;Adipic acid di(2-ethylhexyl) ester, DOA Plasticizer, DOA;Bis(2-ethylhexyl) adipate, 99% 1KG
CAS:103-23-1
MF:C22H42O4
MW:370.57
EINECS:203-090-1
Product Categories:Industrial/Fine Chemicals;Method 506Method Specific;Adipate (Environmental Endocrine Disruptors);Environmental Endocrine Disruptors;Analytical Chemistry;2000/60/EC;Fatty Acid Esters (Plasticizer);Functional Materials;Plasticizer;Building Blocks;C12 to C63;Carbonyl Compounds;Chemical Synthesis;solvent;500 Series Drinking Water Methods;EPA;European Community: ISO and DIN;Esters;Organic Building Blocks
Mol File:103-23-1.mol
Bis(2-ethylhexyl) adipate Structure
Bis(2-ethylhexyl) adipate Chemical Properties
Melting point -67 °C
Boiling point 417 °C
density 0.925 g/mL at 20 °C(lit.)
vapor pressure <0.001 hPa (20 °C)
refractive index n20/D 1.447(lit.)
Fp >230 °F
storage temp. Store below +30°C.
solubility <0.0001g/l
form Liquid
Specific Gravity0.99
color Clear colorless
PH7 (H2O, 20℃)
explosive limit0.24%(V)
Water Solubility immiscible
BRN 1803774
Stability:Stable. Incompatible with oxidizing agents, water, nitrates.
LogP8.94 at 25℃
CAS DataBase Reference103-23-1(CAS DataBase Reference)
IARC3 (Vol. Sup 7, 77) 2000
NIST Chemistry ReferenceDi(2-ethylhexyl)adipate(103-23-1)
EPA Substance Registry SystemDi(2-ethylhexyl) adipate (103-23-1)
Safety Information
Hazard Codes Xi,Xn,T,F
Risk Statements 36/38-40-39/23/24/25-23/24/25-11
Safety Statements 26-36-45-36/37-16-7-24/25
RIDADR UN 1230 3/PG 2
WGK Germany 1
RTECS AU9700000
Autoignition Temperature350 °C DIN 51794
TSCA Yes
HazardClass 9
PackingGroup III
HS Code 29171290
Hazardous Substances Data103-23-1(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit 8410 mg/kg
MSDS Information
ProviderLanguage
Adipic acid bis(2-ethylhexyl) ester English
Bis(2-ethylhexyl) adipate Usage And Synthesis
Chemical Propertiescolourless oily liquid
UsesThe compound is used as a plasticizer for flexible vinyl food wraps and as a solvent for aircraft lubricants.
UsesPlasticizer in polyvinyl chloride films, sheeting, extrusions, and plastisols; solvent and emollient in cosmetics
UsesBis(2-ethylhexyl) adipate also known as dioctyl adipate (DOA) can be used as a plasticizer for improving the impact properties of polymers. DOA is also used to produce clear films for food packaging applications and in synthetic rubber industries due to its compatibility with nitrocellulose and ethylcellulose.
DefinitionChEBI: A diester resulting from the formal condensation of the carboxy groups of adipic acid with 2-ethylhexan-1-ol. It is used as a plasticiser in the preparation of various polymers.
Production MethodsDEHA is manufactured by esterification of adipic acid and 2-ethylhexanol.
General DescriptionColorless to straw-colored liquid with a mild odor. Floats on water.
Air & Water ReactionsBis(2-ethylhexyl) adipate slowly hydrolyzes. Insoluble in water.
Reactivity ProfileBis(2-ethylhexyl) adipate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Can generate electrostatic charges. [Handling Chemicals Safely 1980. p. 250]. Bis(2-ethylhexyl) adipate is incompatible with oxidizing materials and water. Bis(2-ethylhexyl) adipate is also incompatible with nitrates.
Health HazardLiquid may cause mild eye irritation. Repeated or prolonged skin contact may cause irritation.
Fire HazardBehavior in Fire: Use water spray to cool exposed containers.
Flammability and ExplosibilityNonflammable
Safety ProfileModerately toxic by intravenous route. Mildly toxic by ingestion. Experimental reproductive effects. Mutation data reported. An eye and skin irritant. Questionable carcinogen with experimental carcinogenic data. See also ESTERS. When heated to decomposition it emits acrid smoke and irritating fumes.
Bis(2-ethylhexyl) adipate Preparation Products And Raw materials
Raw materialsAdipic acid-->2-Ethylhexanol
Preparation Products2-ethylhexyl hydrogen adipate
Adipic acid 2-Ethylhexyl acrylate 2-Ethylhexanol Dimethyl adipate Adipic dihydrazide SPIRAMYCIN ADIPATE Dioctyl adipate Tris(2-chloroethyl) phosphate ARSENIC ACID TRIETHYL ESTER Dioctyl sebacate Diisooctyl phthalate BUTYL OLEATE Bis(2-ethylhexyl) adipate DIISODECYL ADIPATE Methyl acrylate Bis(2-ethylhexyl) phthalate Dimethyl succinate Dioctyl terephthalate

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