2,2',7,7'-Tetrabromo-9,9'-spirobifluorene

2,2',7,7'-Tetrabromo-9,9'-spirobifluorene Basic information
Product Name:2,2',7,7'-Tetrabromo-9,9'-spirobifluorene
Synonyms:2,2',7,7'-TETRABROMO-9,9'-SPIROBIFLUORENE;2,2'',7,7''-TETRABROMO-9,9''-SPIRO-BIFLUOROENE;2,2'',7,7''-TETRABROMO-9,9''-SPIROBI[9H-FLUORENE];2,2',7,7'-Tetrabromo-9,9'-spirobiflurene;2,2',7,7'-Tetrabromo;9,9'-Spirobi[9H-fluorene], 2,2',7,7'-tetrabroMo- 2,2',7,7'-TetrabroMo-9,9'-spirobi[9H-fluorene];2,2',7,7'-TetrabroMo-9,9'-Spirobifluorene,TetrabroMo-9,9'-Spirobifluorene;TetrabroMo-9,9'-spirobifl
CAS:128055-74-3
MF:C25H12Br4
MW:631.98
EINECS:672-610-0
Product Categories:Fluorene Series;Fluorene Derivatives
Mol File:128055-74-3.mol
2,2',7,7'-Tetrabromo-9,9'-spirobifluorene Structure
2,2',7,7'-Tetrabromo-9,9'-spirobifluorene Chemical Properties
Melting point 395-400°C
Boiling point 633.7±55.0 °C(Predicted)
density 2.12±0.1 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
solubility Chloroform
form Solid
color White to Off-White
CAS DataBase Reference128055-74-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 22-36
Safety Statements 26
WGK Germany 3
HS Code 29039990
MSDS Information
2,2',7,7'-Tetrabromo-9,9'-spirobifluorene Usage And Synthesis
Description2,2′,7,7′-Tetrabromo-9,9′-spirobifluorene is a spirobifluorene (SBF) derivative and is used as a blue-emitting material in electroluminescent devices. The spirobifluorene linkage in the molecule helps in decreasing the crystallization tendency and also increases the colour stability by preventing the formation of aggregates or excimers. They possess high photoluminescence efficiency and good chemical stability.
Chemical PropertiesWhite to light yellow powder
Uses2,2',7,7'-Tetrabromo-9,9'-spirobifluorene is used in the preparation of OLEDs using amorphous compounds with spiro-bifluorene core.
Uses2,2'',7,7''-Tetrabromo-9,9''-spirobifluorene is used in the preparation of OLEDs using amorphous compounds with spiro-bifluorene core.
ApplicationBlue light emitting material in Organic Light Emitting Diodes (OLEDs).
General Description2,2′,7,7′-Tetrabromo-9,9′-spirobifluorene is a spirobifluorene (SBF) derivative and is used as a blue-emitting material in electroluminescent devices. The spirobifluorene linkage in the molecule helps in decreasing the crystallization tendency and also increases the colour stability by preventing the formation of aggregates or excimers. They possess high photoluminescence efficiency and good chemical stability.
2,2',7,7'-Tetrabromo-9,9'-spirobifluorene Preparation Products And Raw materials
Raw materials2,7-Dibromo-9,9'-spiro-bifluorene-->9,9'-Spirobi[9H-fluorene]
Preparation Products2,2',7,7'-Tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9'-spirobifluorene
CHLORODIBROMOMETHANE 2-Bromo-9,9-diphenylfluorene Ethyl bromodifluoroacetate 4,4'-Sulphonylbis(2,6-dibromophenol) 2-Bromo-9,9-dimethylfluorene Decabromodiphenyl Ethane 2,2'-DIBROMO-9,9'-SPIROBIFLUORENE Tetrabromophthalic anhydride Tetrabromobisphenol A 2-Bromofluorene 9,9'-Spirobi[9H-fluorene] 2,7-Dibromo-9,9'-spiro-bifluorene 2-Bromo-9,9'-spirobi[9H-fluorene] 2,7-Dibromo-9,9-dimethylfluorene 2,7-Dibromo-9,9-diphenylfluororene 2,7-Dibromofluorene 2,2',7,7'-Tetrabromo-9,9'-spirobifluorene Dibromomethane

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