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Pentamethylcyclopentadienyltitanium trichloride

Pentamethylcyclopentadienyltitanium trichloride Basic information
Product Name:Pentamethylcyclopentadienyltitanium trichloride
Synonyms:eta5-Pentamethylcyclopentadienyl;Trichloro(pentamethylcyclopentadienyl)titanium(Ⅳ);pentamethylcyclopentadienyltitaniumtrochloride;Titanium, eta5-pentamethylcyclopentadienyl trichloride)-;TRICHLORO(PENTAMETHYLCYCLOPENTADIENYL)TITANIUM(IV);(PENTAMETHYLCYCLOPENTADIENYL)TITANIUM(IV) TRICHLORIDE;PENTAMETHYLCYCLOPENTADIENYLTITANIUM TRICHLORIDE;PENTAMETHYLCYCLOPENTADIENE TITANIUM TRICHLORIDE
CAS:12129-06-5
MF:C10H15Cl3Ti
MW:289.45
EINECS:
Product Categories:metallocene;Catalysts for Organic Synthesis;Classes of Metal Compounds;Half Metallocenes;Homogeneous Catalysts;Metallocenes;Synthetic Organic Chemistry;Ti (Titanium) Compounds;Titanium Alkoxides, etc. (Homogeneous Catalysts);Transition Metal Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Titanium
Mol File:12129-06-5.mol
Pentamethylcyclopentadienyltitanium trichloride Structure
Pentamethylcyclopentadienyltitanium trichloride Chemical Properties
Melting point 200 °C (dec.) (lit.)
Boiling point 190-220 °C(Press: 4-7 Torr)
form crystal
color red
Water Solubility reacts
Sensitive Moisture Sensitive
Hydrolytic Sensitivity7: reacts slowly with moisture/water
CAS DataBase Reference12129-06-5(CAS DataBase Reference)
NIST Chemistry Reference«eta»5-Pentamethylcyclopentadienyl titanium trichloride(12129-06-5)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3
TSCA No
HazardClass 8
PackingGroup II
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Pentamethylcyclopentadienyltitanium trichloride Usage And Synthesis
DescriptionTrichloro(pentamethylcyclopentadienyl)titanium(IV) is a versatile catalyst for transesterification reactions and styrene polymerization.
Chemical PropertiesPentamethylcyclopentadienyl)titanium(IV) Trichloride is a red to bordeaux crystals.
UsesPentamethylcyclopentadienyl)titanium(IV) Trichloride is used as a catalyst in Transesterification reactions and styrene polymerization. It is also used as Piano-stool catalyst.
General DescriptionPentamethylcyclopentadienyltitanium trichloride has been shown to have mononuclear structure and high molecular weight, which can be confirmed by its crystal x-ray diffraction pattern. It belongs to the class of syndiotactic compounds and has an MM value of 1.3 g/mol. It also has a high degree of crystallinity, which can be seen from its diffraction pattern on a hexamethylenetetramine plate.
PENTAKIS(DIMETHYLAMINO)TANTALUM PentaMethylcyclopentadienyltris (diMethylaMino)titaniuM(IV) Pentamethylcyclopentadienyltantalum tetrachloride ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98 PENTAMETHYLCYCLOPENTADIENYLBIS(TRIPHENY& PENTAMETHYLCYCLOPENTADIENYLIRON DICARBONYL DIMER DICARBONYL(PENTAMETHYLCYCLOPENTADIENYL)CHROMIUM DIMER Pentamethylcyclopentadienyl zirconium trichloride CYCLOPENTADIENYLTITANIUM TRICHLORIDE TITANIUM TITANIUM(III) CHLORIDE-ALUMINUM(III) CHLORIDE Hexachlorocyclopentadiene 1,2,3,4-TETRAMETHYL-1,3-CYCLOPENTADIENE SODIUM CYCLOPENTADIENIDE Rutile Pentamethylcyclopentadienyltitanium trichloride 1,2,3,4,5-Pentamethylcyclopentadiene TITANIUM(II) CHLORIDE
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