Ethylene glycol diacetate

Ethylene glycol diacetate Basic information
Product Name:Ethylene glycol diacetate
Synonyms:Ethylene Glycol Diacetate (EGDA);Ethylene glycol diacetate, 99% 2.5LT;1,2-Diacetoxyethane 1,2-Ethanediol Diacetate Ethylene Diacetate Glycol Diacetate;ETHYLENE GLYCOL DIACETATE FOR SYNTHESIS;1,2-Ethanediol,1,2-diacetate;Aceticacid2-acetoxy-ethylester;CH3C(O)OCH2CH2OC(O)CH3;diacetated’ethyleneglycol
CAS:111-55-7
MF:C6H10O4
MW:146.14
EINECS:203-881-1
Product Categories:Organics;DBE
Mol File:111-55-7.mol
Ethylene glycol diacetate Structure
Ethylene glycol diacetate Chemical Properties
Melting point -41 °C (lit.)
Boiling point 186-187 °C (lit.)
density 1.104 g/mL at 20 °C (lit.)
vapor density 5.04 (vs air)
vapor pressure 0.2 mm Hg ( 20 °C)
refractive index n20/D 1.431(lit.)
Fp 198 °F
storage temp. 2-8°C
solubility 160g/l
form Liquid
color blue
Odorat 100.00 %. green floral estery alcoholic
Odor Typegreen
explosive limit1.6%, 135°F
Water Solubility 160 g/L (20 ºC)
Merck 14,3799
BRN 1762308
LogP0.1 at 40℃
CAS DataBase Reference111-55-7(CAS DataBase Reference)
NIST Chemistry Reference1,2-Ethanediol, diacetate(111-55-7)
EPA Substance Registry SystemEthylene glycol diacetate (111-55-7)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 36/37/38
Safety Statements 26-36-24/25-22
WGK Germany 1
RTECS KW4025000
3
Autoignition Temperature899 °F
TSCA Yes
HS Code 29153900
Hazardous Substances Data111-55-7(Hazardous Substances Data)
ToxicityLD50 orally in rats: 6.86 g/kg (Smyth)
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Ethylene glycol diacetate Usage And Synthesis
Chemical Propertiesclear liquid
UsesEthylene glycol diacetate may be used as an acyl donor for the in situ generation of peracetic acid, during the chemoenzymatic synthesis of caprolactone. It may be employed as a precursor for the enzymatic synthesis of poly (ethylene glutarate).
UsesEGDA imparts excellent flow properties in baking lacquers and enamels and where thermoplastic acrylic resins are used. It is also a good solvent for cellulosic coatings and can be used in some ink systems such as screen inks. It has found use as a perfume fixative, and has reported applications in waterborne adhesives.
UsesSolvent for oils, cellulose esters, explosives, etc.
General DescriptionColorless liquid with a mild pleasant odor. Density 9.2 lb /gal. Flash point 191°F. Boiling point 369°F. Combustible but requires some effort to ignite. Used in the manufacture of perfumes, printing ink, lacquers and resins.
Air & Water ReactionsWater soluble.
Reactivity ProfileEthylene glycol diacetate reacts with aqueous acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction with caustic solutions. Flammable hydrogen is generated with alkali metals and hydrides.
Health HazardInhalation is not hazardous. Liquid causes mild irritation of eyes. Ingestion causes stupor or coma.
Fire HazardEthylene glycol diacetate is combustible.
Flammability and ExplosibilityNotclassified
Safety ProfileModerately toxic by intraperitoneal route. Mildly toxic by ingestion and skin contact. An eye irritant. Combustible when exposed to heat or flame; can react with oxidzing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
Purification MethodsDry the di-ester with CaCl2, filter (excluding moisture) and fractionally distil it under reduced pressure. [Beilstein 2 IV 1541.]
Ethylene glycol diacetate Preparation Products And Raw materials
Raw materials1,2-Dibromoethane-->Potassium Acetate
Preparation Productspolyacrylamide emulsifier-->1,2-DIIODOETHANE-->2-Iodoethanol
ETHYLENE GLYCOL MONOSTEARATE Ethyl 2-(Chlorosulfonyl)acetate BETA-D-RIBOPYRANOSE 1,2,3,4-TETRAACETATE SORBITOL HEXAACETATE Inositol nicotinate PEN Dibenzoyltartaric acid Ethyleneamines Diethylene glycol dibenzoate 1,2-Diformyloxyethane 1,2,3,4,6-Penta-O-acetyl-b-D-glucopyranose Glycol dimercaptoacetate 6-AZAURIDINE 2',3',5'-TRIACETATE Ethyl ethoxyacetate Ethylene glycol monoethyl ether acetate 2-Acetamido-2-deoxy-1,3,4,6-tetra-0-acetyl-alpha-D-glucopyranose 2,3-Di-O-para-toluoyl-D-tartaric acid Polyethylene-polypropylene glycol diacetate

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