4',4''(5'')-DI-TERT-BUTYLDIBENZO-18-CROWN-6

4',4''(5'')-DI-TERT-BUTYLDIBENZO-18-CROWN-6 Basic information
Product Name:4',4''(5'')-DI-TERT-BUTYLDIBENZO-18-CROWN-6
Synonyms:4',4''(5'')-DI-TERT-BUTYLDIBENZO-18-CROWN-6;AR,AR'-DI-TERT-BUTYLDIBENZO-18-CROWN-6;14)-bis(1,1-dimethylethyl)-ro-13(or2;4',4''(5'')-di-tert-butyldibenzo-18-crown-6, mixed isomers;4',4pi(5pi)-Di-tert-butyldibenzo-18-crown-6;4,4'-Di-tert-butyldibenzo-18-crown-6;4',4''(5'')-Di-tert-butyldibenzo-18-crown-6,94%;4',4''(5'')-di-tert-butyldibenzo-18-crown-6, mixed iso
CAS:29471-17-8
MF:C28H40O6
MW:472.61
EINECS:
Product Categories:Crown Ethers;Chelation/Complexation Compounds;Synthetic Reagents
Mol File:29471-17-8.mol
4',4''(5'')-DI-TERT-BUTYLDIBENZO-18-CROWN-6 Structure
4',4''(5'')-DI-TERT-BUTYLDIBENZO-18-CROWN-6 Chemical Properties
Melting point 112-116 °C
Boiling point 533.38°C (rough estimate)
density 1.0542 (rough estimate)
refractive index 1.6000 (estimate)
BRN 1667522
EPA Substance Registry SystemDibenzo[b,k][1,4,7,10,13,16]hexaoxacyclooctadecin, 2,13(or 2,14)-bis(1,1-dimethylethyl)-6,7,9,10,17,18,20,21-octahydro- (29471-17-8)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-36/38-22
Safety Statements 26-36-36/37
RIDADR 2811
WGK Germany 3
RTECS HP5386500
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29329990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
4',4''(5'')-DI-TERT-BUTYLDIBENZO-18-CROWN-6 Usage And Synthesis
Description4′,4″(5″)-Di-tert-butyldibenzo-18-crown-6 is a hydrophobic crown ether compound. This crown ether is potentially useful in studies of ion transport through non-polar regions and membranes, and has been described in the design of microsensor devices for ammonia determination based upon ammonia-mediated deprotonation of a pH indicator followed by sequestering of ammonium within the 4′,4″(5″)-Di-tert-butyldibenzo-18-crown-6 sphere.
Chemical PropertiesOff-white powder
Uses4'',4''''(5'''')-Di-tert-butyldibenzo-18-crown-6 is a hydrophobic crown ether compound..
4',4''(5'')-DI-TERT-BUTYLDIBENZO-18-CROWN-6 Preparation Products And Raw materials
1,5-BIS(O-HYDROXYPHENOXY)-3-OXAPENTANE 2-(2-HYDROXYETHOXY)PHENOL Dibenzo-18-crown-6 3-tert-Butylphenol tert-Butylcatechol 4,4'-DI-TERT-BUTYLDIBENZO-18-CROWN-6 = AR,AR'-DI-TERT-BUTYLDIBENZO-18-CROWN-6 O,O'-BIS(2-HYDROXYETHOXY)BENZENE 18-Crown-6 2-(4-tert-butylphenoxy)ethanol 4',4''(5'')-DI-TERT-BUTYLDIBENZO-18-CROWN-6

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