VANADIUM(IV) OXIDE

VANADIUM(IV) OXIDE Basic information
Description References
Product Name:VANADIUM(IV) OXIDE
Synonyms:Vanadium oxide (VO2);vanadiumoxide(vo2);VO2;VANADIUM TETRAOXIDE;VANADIUM OXIDE;VANADIUM(IV) OXIDE;VANADIUM DIOXIDE;Vanadium(Ⅳ)oxide
CAS:12036-21-4
MF:O2V
MW:82.94
EINECS:234-841-1
Product Categories:metal oxide
Mol File:12036-21-4.mol
VANADIUM(IV) OXIDE Structure
VANADIUM(IV) OXIDE Chemical Properties
Melting point 1967°C
density 4.339 g/mL at 25 °C(lit.)
form Powder
Specific Gravity4.339
color black
Water Solubility Insoluble in water.
Exposure limitsNIOSH: Ceiling 0.05 mg/m3
CAS DataBase Reference12036-21-4(CAS DataBase Reference)
EPA Substance Registry SystemVanadium oxide (VO2) (12036-21-4)
Safety Information
Hazard Codes Xi
Risk Statements 36/38
Safety Statements 26-37/39
RIDADR UN3285
WGK Germany 3
10-23
HazardClass 6.1
PackingGroup II
HS Code 28253090
MSDS Information
ProviderLanguage
ALFA English
VANADIUM(IV) OXIDE Usage And Synthesis
DescriptionVanadium (IV) dioxide is a kind of inorganic compound with its chemical formula being VO2. It can undergo a phase transition at a normal temperature (~66 °C). Its electrical resistivity and opacity can also change several fold. These special properties make it have many applications. For example, it can be used in chemical sensors, energy-conserving coatings, transparent conductors and switching materials. It can also be used as a stationary optical shutter, optical modulators, cameras and data storage. Moreover, it can be applied to the missile guidance system due to its infrared modulation capability. It can also be used to make thin films which have been used in electro-optical switches, micro-optical switch, passive smart radiators and sunshields for spacecraft. It can also be used in phase change computing and memory.
Referenceshttps://en.wikipedia.org/wiki/Vanadium(IV)_oxide
https://www.alfa.com/en/catalog/022957/
Chemical PropertiesBlue-black powder. Insoluble in water; soluble in alkalies and acids.
Chemical PropertiesVanadium(IV) Oxide (vanadium dioxide, VO2) is a blue-black solid, having a distorted rutile (TiO2) structure. It can be prepared from the reaction of V2O5 at the melting point with sulfur or carbonaceous reductants such as sugar or oxalic acid. The dioxide slowly oxidizes in air. Vanadium dioxide dissolves in acids to give the stable (VO)2+ ions and in hot alkalies to yield vanadate(IV) species, eg, (HV2O5)?.
UsesVanadium(IV) oxide is used in chemical sensors, energy-conserving coatings, transparent conductors and switching materials. It acts as a stationary optical shutter, optical modulators, cameras and data storage. As infrared modulators, it is used for the missile guidance systems. Thin films made up of vanadium dioxide find applications in electro-optical switches, micro-optical switch, passive smart radiators and sunshields for spacecraft.
DefinitionChEBI: Vanadium dioxide is a vanadium oxide.
HazardToxic and irritating.
Flammability and ExplosibilityNonflammable
VANADIUM(IV) OXIDE Preparation Products And Raw materials
RUBIDIUM VANADATE (META) NICKEL VANADATE MAGNESIUM VANADIUM OXIDE,MAGNESIUM VANADIUM OXIDE, 99.9% (METALS BASIS) ZINC ORTHOVANADATE CESIUM METAVANADATE Lithium vanadium oxide, 99.9% (metals basis),LITHIUM VANADIUM OXIDE AMMONIUM MOLYBDATE METAVANADATE REAGENT Potassium metavanadate SILVER VANADIUM OXIDE Ammonium vanadium oxide CADMIUM VANADATE SODIUM METAVANADATE HYDRATE Vanadium(V) oxide VANADIUM OXIDE,VANADIUM (IV) OXIDE VANADIUM(IV) OXIDE lead vanadium oxide VANADIUM OXIDE CALCIUM VANADATE

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