SILICON (IV) IODIDE

SILICON (IV) IODIDE Basic information
Description Reference
Product Name:SILICON (IV) IODIDE
Synonyms:SILICON IODIDE;SILICON TETRAIODIDE, 99.9+%;Silicon(IV)iodide,99.9%(metalsbasis);Silicon(IV)iodide(99.9%-Si);SILICON (IV) IODIDE;SILICON TETRAIODIDE;TETRAIODOSILANE;SiI4
CAS:13465-84-4
MF:I4Si
MW:535.7
EINECS:236-706-2
Product Categories:metal halide
Mol File:13465-84-4.mol
SILICON (IV) IODIDE Structure
SILICON (IV) IODIDE Chemical Properties
Melting point 120 °C
Boiling point 287.4 °C
density 4.198
Fp 287.5°C
form Lumps
color White
Specific Gravity4.198
Water Solubility Soluble in organic solvents. Insoluble in water.
Sensitive Moisture Sensitive
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
CAS DataBase Reference13465-84-4(CAS DataBase Reference)
EPA Substance Registry SystemSilane, tetraiodo- (13465-84-4)
Safety Information
Hazard Codes T
Risk Statements 24/25-34-42/43-61
Safety Statements 26-36/37/39-45-53
RIDADR 3260
TSCA Yes
HazardClass 8
PackingGroup II
MSDS Information
ProviderLanguage
ALFA English
SILICON (IV) IODIDE Usage And Synthesis
DescriptionSilicon Iodide is the iodide of silicon. It is a precursor to silicon amide. It is also applied in the manufacture and etching of silicon in microelectronics. Selective area regrowth of silicon-doped GaAs has been successfully achieved by chemical beam epitaxy (CBE) on dry etched trench structures. Silicon tetraiodide is useful for the above process in abrupt to manipulate metal-semiconductor field effect transistor (MESFET) and heterostructure field effect transistor (HFET). Silicon iodide can also be reduced as the source to form pure silicon and hydrogen iodide.
Reference
  1. Izumi, Shigekazu, et al. Journal of Crystal Growth 175.175(1997): 404-410.
  2. http://jes.ecsdl.org/content/104/11/663.short
  3. https://en.wikipedia.org/wiki/Silicon_tetraiodide
Chemical PropertiesWhite crystals. Noncombustible.
UsesSilicon(IV) iodide is used as a precursor to prepare silicon amides. It finds application in the manufacture and etching of silicon in microelectronics.
HazardToxic by ingestion and inhalation, irritant to tissue.
SILICON (IV) IODIDE Preparation Products And Raw materials
Barium iodide SILICON TETRABROMIDE SILICON TETRAACETATE CALCIUM SULFIDE ZINC NITRIDE Tetrachlorosilane TIN(IV) IODIDE Boron nitride DIIODOSILANE SILICON (IV) IODIDE

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