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| | (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Basic information | | Reaction |
| Product Name: | (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& | | Synonyms: | (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL&;(S,S)-N,N-BIS(3,5-DITBUTYLSALICYLIDENE)-;(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]aluminum(III)chloride,98%;(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride;(s,s)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum(iii) chloride;(S,S)Salen AI;Aluminum,chloro[[2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)- (9CI) | | CAS: | 307926-51-8 | | MF: | C36H52AlClN2O2 | | MW: | 607.254 | | EINECS: | | | Product Categories: | Jacobsen Metal | | Mol File: | 307926-51-8.mol |  |
| | (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Chemical Properties |
| Melting point | >350 °C(lit.) | | form | Powder | | color | yellow |
| Hazard Codes | Xn | | Risk Statements | 20/21/22 | | Safety Statements | 26-36 | | WGK Germany | 3 |
| | (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Usage And Synthesis |
| Reaction | Aluminum salen complexes as catalysts for the kinetic resolution of terminal epoxides via carbon dioxide coupling.
Efficient synthesis of bio-renewable polyesters and cyclic carbonates through tandem catalysis.
Catalyst used for the asymmetric hydrocyanation of nitroolefins.
Catalyst used in the reaction of epoxides with heterocumulenes.
| | Uses | (S,S)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride can be used as a chiral catalyst:
- In the preparation of substituted hydroxyalkyl aminooxazole derivatives by reacting isocyanides with aldehydes.
- In the cyanation of α,β-unsaturated imides to yield saturated imides.
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| | (S S)-N N'-BIS(3 5-DI-TERT-BUTYLSALICYL& Preparation Products And Raw materials |
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