ChemicalBook Product Catalog Chemical Reagents Organic reagents Ionic Liquids 1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE

1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE

1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE Basic information
Description Referrence
Product Name:1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE
Synonyms:Ethyl-3-MethyliMidazoliuM bis(trifluoroMethylsulfonyl;1-Ethyl-3-MethyliMidazoliuM bis(trifluoroMethylsulfonyl)iMide >=97.0% (NMR);1-Ethyl-3-MethyliMidazoliuM bis(trifluoroMethylsulfonyl)iMide produced by BASF, >=98% (H-NMR);3-Ethyl-1-methyl-1H-imidazol-3-ium bis((trifluoromethyl)sulfonyl)amide;Basionics? HP 01;1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide >=98% (HPLC);1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE, 99% [EMIIM];1-ETH.-3-MET-IMIDAZOLIUM-BIS-(TRIFLUORO MET-SULFONYL)IMIDATE
CAS:174899-82-2
MF:C6H11N2.C2F6NO4S2
MW:391.312
EINECS:700-235-5
Product Categories:organic amine
Mol File:174899-82-2.mol
1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE Structure
1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE Chemical Properties
Melting point ≥?15 °C (lit.)
Boiling point 543.6 °C
density 1,53 g/cm3
vapor pressure 0.004-0.007Pa at 140.9-150.9℃
refractive index 1.4220-1.4260
Fp >200 ºC
storage temp. Store below +30°C.
Water Solubility Insoluble in water
form liquid
Specific Gravity1.53
color colorless to pale yellow
LogP-0.73--0.65 at 25℃ and pH6.1
ECW4.7 V
Safety Information
Hazard Codes T,N
Risk Statements 24/25-34-51/53
Safety Statements 26-36/37/39-45-61
RIDADR UN 2922
WGK Germany 3
F 10
HS Code 2935 90 90
ToxicityLD50 orally in Rabbit: > 50 - 300 mg/kg
MSDS Information
1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE Usage And Synthesis
DescriptionIt is a typical ionic liquid usually used as the solvent in the organic synthesis and chemical industry. For example, this chemical can act as the solvent for dissolving CO2 gas.1 This substance may also function as the solvent for dissolving the electroactive oxygen, thus allowing for the study of electrochemical reduction of oxygen by cyclic voltammetry at a gold microdisk electrode.2 Moreover, determination of ammonia based on electro-oxidation of hydroquinone has been carried out by using this compound as the solvent.3 Besides, nanoparticles of ZnO with the wurtzite structure have been synthesized via a microwave through the decomposition of zinc acetate dihydrate in 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide as a solvent.4
Referrence
  1. Schilderman, A. M.; Raeissi, S.; Peters, C. J., Solubility of carbon dioxide in the ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. Fluid Phase Equilib. 2007, 260, 19-22.
  2. Buzzeo, M. C.; Klymenko, O. V.; Wadhawan, J. D.; Hardacre, C.; Seddon, K. R.; Compton, R. G., Voltammetry of oxygen in the room-temperature ionic liquids 1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide and hexyltriethylammonium bis((trifluoromethyl)sulfonyl)imide: One-electron reduction to form superoxide. Steady-state and transient behavior in the same cyclic voltammogram resulting from widely different diffusion coefficients of oxygen and superoxide. J. Phys. Chem. A 2003, 107, 8872-8878.
  3. Giovanelli, D.; Buzzeo, M. C.; Lawrence, N. S.; Hardacre, C.; Seddon, K. R.; Compton, R. G., Determination of ammonia based on the electro-oxidation of hydroquinone in dimethylformamide or in the room temperature ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. Talanta 2004, 62, 904-911.
  4. Goharshadi, E. K.; Ding, Y.; Nancarrow, P., Green synthesis of ZnO nanoparticles in a room-temperature ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. J. Phys. Chem. Solids 2008, 69, 2057-2060.
Conductivity6.63 mS/cm
Chemical PropertiesClear colorless liquid
UsesIonic Liquids for Energy Storage Applications
Uses1-Ethyl-3-methylimidazolium bis(Trifluoromethylsulfonyl)imide is an ionic liquid; used in method for regulating thermal response temperature of ionic liquid gel and thermal response ionic liquid gel.
General Description1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [EMIM][N(Tf)2] is a room temperature ionic liquid (RTIL). ([EMIM][N(Tf)2]) as a non-aqueous solvent, is advantageous over traditional aprotic polar organic solvents in electrochemical investigation of electroactive species since it has low vapor pressure, high thermal stability, good conductivity and a wide electrochemical window. [EMIM][N(Tf)2] shows good solubility in CO2.
1,3-diMethyliMidazoliuM bis((trifluoroMethyl)sulfonyl)iMide 1-Butyl-3-methylimidazolium trifluoromethansulfonate 1-ETHYL-3-METHYLIMIDAZOLIUM TRIFLUOROACETATE 1,3-DIALLYLIMIDAZOLIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE 1-(2-HYDROXYETHYL)-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE 1-(1H,1H,2H,2H-PERFLUOROHEXYL)-3-METHYL-IMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE 1-ALLYL-3-ETHYLIMIDAZOLIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE 1-HEXYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE 1-ALLYL-3-BUTYLIMIDAZOLIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE 1-ETHYL-2,3-DIMETHYLIMIDAZOLIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE 1-PROPYL-3-METHYL-IMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE 1,3-Bis(cyanomethyl)imidazolium bis(trifluoromethylsulfonyl)imide 1-BUTYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOR 1-ETHYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE 1-BUTYL-2,3-DIMETHYLIMIDAZOLIUM BIS(TRIFLUOROMETHANESULFONYL)IMIDE 1,3-Bis(3-cyanopropyl)imidazolium bis(trifluoromethylsulfonyl)imide 1-(3-Cyanopropyl)-3-methylimidazolium bis(trifluoromethylsulfonyl)amide 3-METHYL-1-OCTADECYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE
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