Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Basic information

Product Name:	Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
Synonyms:	Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium;Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-;DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE;DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER;BIS[(PENTAMETHYLCYCLOPENTADIENYL)DICHLORO-RHODIUM];PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&;PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER
CAS:	12354-85-7
MF:	C20H30Cl4Rh210*
MW:	618.08
EINECS:
Product Categories:	metallocene;Catalysis and Inorganic Chemistry;Catalysts for Organic Synthesis;Classes of Metal Compounds;Chemical Synthesis;Rhodium;Homogeneous Catalysts;Metal Complexes;Rh (Rhodium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Rh
Mol File:	12354-85-7.mol

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties

Melting point	>300°C
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	Chloroform (Sparingly), Methanol (Slightly)
form	crystal
color	red
Water Solubility	Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Stability:	Hygroscopic
NIST Chemistry Reference	Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7)

Safety Information

MSDS Information

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Usage And Synthesis

Reaction	Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill. Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids. Catalyst used in the asymmetric transfer hydrogenation of imines in water. Facile rhodium-catalyzed synthesis of fluorinated pyridines. Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.
Chemical Properties	burgundy solid
Uses	Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A
Uses	Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Preparation Products And Raw materials

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