(S)-1,2,4-Butanetriol

(S)-1,2,4-Butanetriol Basic information
Description
Product Name:(S)-1,2,4-Butanetriol
Synonyms:(S)-1,2,4-Butanetriol,95%,99% ee;(2S)-(-)-1,2,4-Trihydroxybutane;ASTM D6584 1,2,4-Butanetriol Solution ;(2S)-BUTANE-1,2,4-TRIOL;1,2,4-BUTANETRIOL, (S);BUTANETRIOL(CAS#: 42890-76-6),INT STD#1&;(S)-()-1,2,4-Butanetriol 98%;(S)-(-)-1,2,4-Butanetriol(ee/glc)
CAS:42890-76-6
MF:C4H10O3
MW:106.12
EINECS:610-080-4
Product Categories:Organic Building Blocks;Polyols;Chiral Building Blocks;Simple Alcohols (Chiral);Synthetic Organic Chemistry;Chiral Building Blocks
Mol File:42890-76-6.mol
(S)-1,2,4-Butanetriol Structure
(S)-1,2,4-Butanetriol Chemical Properties
alpha -30 º (c=1, MeOH)
Boiling point 150 °C0.04 mm Hg(lit.)
density 1.19 g/mL at 25 °C(lit.)
refractive index n20/D 1.475(lit.)
Fp >110°C
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly), Methanol (Sparingly), Water (Slightly)
form Oil
pka14.02±0.20(Predicted)
Specific Gravity1.190
color Colourless
optical activity[α]19/D 28±2, c = 1 in methanol
Water Solubility soluble
Sensitive Hygroscopic
BRN 1719408
Stability:Hygroscopic
CAS DataBase Reference42890-76-6(CAS DataBase Reference)
Safety Information
Hazard Codes F,Xn
Risk Statements 36/37/38-41-20/21/22-11
Safety Statements 23-24/25-39-26-16-36/37-28-33-29-9
RIDADR UN 3316 9/PG 2
WGK Germany 3
3-10-21
HS Code 2905490090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
(S)-1,2,4-Butanetriol Usage And Synthesis
Description

(S)-(-)-1,2,4-Butanetriol can be prepared via reduction of (S)-malic acid in the presence of borane-dimethyl sulfide. (S)-(-)-1,2,4-Butanetriol may be used as a starting material in the enantioselective total syntheses of (+)-azimine and (+)-carpaine. It can also be used to prepare the organic building blocks (+)-3,4-epoxy-1-butanol, (2S,4S)-4-(hydroxymethyl)-2-ferrocenyl-1,3-dioxan, (S)-1,2,4-triacetoxybutane via acetylation with acetic anhydride, and (S)-1,2,4-tris-(3,5-dinitrobenzoy1oxy)butane via esterification with 3,5-dinitrobenzoyl chloride, and so on.

Chemical Propertiesclear colorless viscous liquid
UsesGlycerophospholipids act as regulators of various enzyme activities, and can be used as biological markers to indicate pathological states.
DefinitionChEBI: 2-deoxyerythritol is a secondary alcohol.
(S)-1,2,4-Butanetriol Preparation Products And Raw materials
Raw materials2-Butanol, 1,4-bis(phenylmethoxy)-, (2S)--->Dimethyl malate
rac-(2R*)-1,2,4-Butanetriol D-RIBULOSE 1,2,4-Butanetriol 2,4-bismethacrylate 1,2,4-Butanetriol trisisocrotonate 1,2:5,6-Bis-O-(1-methylethylidene)-D-mannitol HEXA(2-CYANOETHOXY) CYCLOHEXANE EPI-INOSITOL 1,2,3-Butanetriol 1,2-bisacrylate CYMARIN 2-Naphthyl-beta-D-galactopyranoside SODIUM DIHYDROXYTARTRATE 1,2,3-Butanetriol trinitrate adipiodone, dimeglumine salt [R,(+)]-3-Methyl-1,2,3-butanetriol 1,2,3-tris(3,5-dinitrobenzoate) [S,(+)]-2-Methyl-1,2,4-butanetriol 1,4-bis(p-nitrobenzoate) 2-KETO-D-GLUCONIC ACID HEMICALCIUM SALT 1,2,4-Butanetriol 1,2-bisacrylate 2,5-O-METHYLENE-D-MANNITOL

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