1,1-Di(tert-butylperoxy)cyclohexane

1,1-Di(tert-butylperoxy)cyclohexane Basic information
Product Name:1,1-Di(tert-butylperoxy)cyclohexane
Synonyms:1,1-BIS(T-BUPEROXY)CYCLOHEXANE, 80 WT. %;1 1-BIS(T-BUTYLPEROXY)CYCLOHEXANE TECH&;50%solutioninmineraloil;1,1-Di(tert-butylperoxy)cyclohexane, 50% solution in mineral oil;1,1-Di-(tert.-butylperoxy)-cyclohexan;Cyclohexylidenebis[(1,1-dimethylethyl)peroxide];Luperox(R) 331P80;1,1-Bis(tert-butylperoxy)cyclohexane (Luperox(R) 331M80) solution
CAS:3006-86-8
MF:C14H28O4
MW:260.37
EINECS:221-111-2
Product Categories:Industrial/Fine Chemicals
Mol File:3006-86-8.mol
1,1-Di(tert-butylperoxy)cyclohexane Structure
1,1-Di(tert-butylperoxy)cyclohexane Chemical Properties
Melting point 65 °C (SADT)
Boiling point 52-54 °C (0.1 mmHg)
density 0.891 g/mL at 25 °C
vapor pressure 4.88hPa at 25℃
refractive index n20/D 1.435
Fp 155 °F
storage temp. 2-8°C
form Liquid
color Clear
Water Solubility miscible
LogP7.2 at 25℃
CAS DataBase Reference3006-86-8(CAS DataBase Reference)
EPA Substance Registry SystemPeroxide, 1,1'-cyclohexylidenebis[2-(1,1-dimethylethyl) (3006-86-8)
Safety Information
Hazard Codes O,N,T
Risk Statements 7-62-50/53-36/37/38-61-65-45-51/53
Safety Statements 17-36/37/39-3/7-14A-61-60-45-26-14-53-62
RIDADR UN 3103 5.2
WGK Germany 2
HazardClass 5.2
PackingGroup II
HS Code 29096000
MSDS Information
ProviderLanguage
Trigonox 22 English
SigmaAldrich English
ACROS English
1,1-Di(tert-butylperoxy)cyclohexane Usage And Synthesis
Chemical Propertiesclear liquid
UsesPolymerization initiator.
Reactivity ProfileThe explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. 1,1-Di(tert-butylperoxy)cyclohexane is unlikely that this derivative would be particularly unstable compared to other peroxides in it's class, Bretherick 2nd ed., p 44 1979.
Flammability and ExplosibilityNotclassified
1,1-Di(tert-butylperoxy)cyclohexane Preparation Products And Raw materials
1 1-BIS(TERT-AMYLPEROXY)CYCLOHEXANE 2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane Dibutyltin oxide n-butylhydroperoxide Monobutyltin oxide Hydrogen peroxide Cyclohexane Buprofezin 2,2-DI(4,4-DI(TERT-BUTYLPEROXY)CYCLOHEXYL)PROPANE, 20 WT% SOLUTION IN ETHYLBENZENE 2,2-Di(tert-butylperoxy)butane tert-Butanol Tetrabutylammonium hydroxide Butyl acetate 1,1-Di(tert-butylperoxy)cyclohexane HYDROXYMETHYLTERT-BUTYLPEROXIDE Dicumyl peroxide Di-tert-butyl peroxide DI-TERT-BUTYL ETHER

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