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| | D-(+)-TURANOSE Basic information |
| | D-(+)-TURANOSE Chemical Properties |
| Melting point | 170 °C (dec.)(lit.) | | alpha | D20 +27.3° +75.8° (c = 4 in water) | | Boiling point | 397.76°C (rough estimate) | | density | 1.4149 (rough estimate) | | refractive index | 75.5 ° (C=4, H2O) | | storage temp. | -20°C Freezer | | solubility | H2O: 0.1 g/mL, clear, colorless | | pka | 12.67±0.10(Predicted) | | form | Solid | | color | White | | Water Solubility | Soluble in water and methanol. | | Merck | 14,9821 | | BRN | 93771 | | CAS DataBase Reference | 547-25-1(CAS DataBase Reference) | | EPA Substance Registry System | D-Fructose, 3-O-.alpha.-D-glucopyranosyl- (547-25-1) |
| | D-(+)-TURANOSE Usage And Synthesis |
| Chemical Properties | White Powder | | Uses | D-Turanose is used as a carbon source by bacteria, fungi, and other organisms. It is involved in intracellular sugar signaling in plant cells. | | Definition | ChEBI: A glycosylfructose isolated from Daphnia magna. | | Purification Methods | Crystallise D(+)-turanose from H2O by addition of EtOH (its solubility is 5.3% in 95% EtOH). Form m 157o is obtained by crystallisation from hot MeOH, and mutarotates from +27.3o to [] 20D +88o (c 4, H2O). The phenylosazone crystallises from 15 parts of 95% EtOH with m 200-205o, [] D 24.5o mutarotating to +33o[24hours, c 0.82, pyridine/EtOH (4:6)]. [Pascu Methods in Carbohydrate Chemistry I 353 1962, Academic Press, Beilstein 17/7 V 213.] In D2O at 36o 1H NMR showed the following ratios: -pyranose (<4), -pyranose (39), -furanose (20) and -furanose (41)[Angyal Adv Carbohydr Chem 42 15 1984]. |
| | D-(+)-TURANOSE Preparation Products And Raw materials |
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