ETHYLDIPHENYLPHOSPHINE

ETHYLDIPHENYLPHOSPHINE Basic information
Product Name:ETHYLDIPHENYLPHOSPHINE
Synonyms:DIPHENYLETHYLPHOSPHINE;ETHYLDIPHENYLPHOSPHINE;Ethyldiphenylphosphine,98%;Ethyldiphenylphosphine,99%;Silicagel, functionalized, Diphenylphosphinoethyl, 0.7 mmol/g;(Diphenylphosphino)ethane;1-(Diphenylphosphino)ethane;NSC 151254
CAS:607-01-2
MF:C14H15P
MW:214.24
EINECS:627-386-9
Product Categories:organophosphorus ligand;Achiral Phosphine;Phosphine Ligands;Synthetic Organic Chemistry;Aryl Phosphine
Mol File:607-01-2.mol
ETHYLDIPHENYLPHOSPHINE Structure
ETHYLDIPHENYLPHOSPHINE Chemical Properties
Boiling point 293 °C(lit.)
density 1.048 g/mL at 25 °C(lit.)
refractive index n20/D 1.614(lit.)
Fp >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Liquid
color Clear colorless
Specific Gravity1.048
Sensitive Air Sensitive
BRN 744253
CAS DataBase Reference607-01-2(CAS DataBase Reference)
EPA Substance Registry SystemPhosphine, ethyldiphenyl- (607-01-2)
Safety Information
Hazard Codes Xn
Risk Statements 22-36/37/38
Safety Statements 26-36
RIDADR 3278
WGK Germany 3
RTECS SY9242500
10-13-23
HazardClass 6.1
PackingGroup III
HS Code 29310099
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
ETHYLDIPHENYLPHOSPHINE Usage And Synthesis
Chemical Propertiesclear colorless liquid
UsesCatalyst for:
  • Three component coupling reactions of arylaldehydes with Me vinyl ketone and phthalimide
  • Regio- and stereoselective hydroalkynylation of methylenecyclopropanes
  • Synthesis of oxazolidines, thiazolidines, pyrrolidines, and indoles
  • Dimer to monomer conversion
  • Tandem Morita-Baylis-Hillman/Michael addition reactions
  • Platinum-catalyzed cyclization
  • Regioselective and stereoselective [3+2] cycloaddition
  • Platinum-catalyzed intermolecular hydroamination
  • Hydroformylation reactions
ETHYLDIPHENYLPHOSPHINE Preparation Products And Raw materials
(Carbomethoxymethyl)triphenylphosphonium bromide Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) (+)-DIOP BIS(2-DIPHENYLPHOSPHINOETHYL)PHENYLPHOSPHINE 1,4-Bis(diphenylphosphino)butane 1,1'-Bis(diphenylphosphino)ferrocene (2-HYDROXYETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE 1,3-Bis(diphenylphosphino)propane Allyltriphenylphosphonium bromide TRIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE 1,5-Bis(diphenylphosphino)pentane (2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE (4-CYANOBENZYL)TRIPHENYLPHOSPHONIUM CHLORIDE [2-(diphenylarsino)ethyl]diphenylphosphine (2-DIMETHYLAMINOETHYL)TRIPHENYLPHOSPHONIUM BROMIDE (CARBOETHOXYMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE HYDRATE (-)-TETRAPHOS 1,6-Bis(diphenylphosphino)hexane

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