ChemicalBook Product Catalog Chemical Reagents Organic reagents Esters Methyl ester compound Methyl DL-mandelate

Methyl DL-mandelate

Methyl DL-mandelate Basic information
Product Name:Methyl DL-mandelate
Synonyms:(+/-)-alpha-Hydroxyphenylacetic acid methyl ester~(+/-)-Mandelic acid methyl ester;DL-MANDELIC ACID METHYL ESTER CRYSTALLINE;(±)-Methylmandelate,97%;alpha-Hydroxyphenylacetic acid methyl ester;Methyl 2-hydroxy-2-phenylacetate;rac-(2R*)-2-Hydroxy-2-phenylacetic acid methyl ester;rac-(R*)-Hydroxyphenylacetic acid methyl ester;rac-(R*)-Phenylhydroxyacetic acid methyl ester
CAS:4358-87-6
MF:C9H10O3
MW:166.18
EINECS:224-434-7
Product Categories:C8 to C9;Carbonyl Compounds;FINE Chemical & INTERMEDIATES;Esters
Mol File:4358-87-6.mol
Methyl DL-mandelate Structure
Methyl DL-mandelate Chemical Properties
Melting point 54-56 °C (lit.)
Boiling point 135 °C/12 mmHg (lit.)
density 1.1756
refractive index 1.5351 (estimate)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
solubility methanol: 0.1 g/mL, clear
pka12.19±0.20(Predicted)
form Solid
color White to Off-White
BRN 2047558
CAS DataBase Reference4358-87-6(CAS DataBase Reference)
NIST Chemistry ReferenceMethyl mandelate(4358-87-6)
EPA Substance Registry SystemBenzeneacetic acid, .alpha.-hydroxy-, methyl ester (4358-87-6)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
TSCA Yes
HS Code 29181980
MSDS Information
ProviderLanguage
Methyl DL-mandelate English
SigmaAldrich English
ACROS English
ALFA English
Methyl DL-mandelate Usage And Synthesis
Chemical Propertieswhite to slightly yellow crystals, crystalline
UsesMethyl DL-Mandelate is a substrate for lipase B from Candida antarctica.
DefinitionChEBI: Mandelic Acid, Methyl Ester is a member of benzenes.
Synthesis Reference(s)Synthetic Communications, 16, p. 331, 1986 DOI: 10.1080/00397918608076314
Methyl DL-mandelate Preparation Products And Raw materials
Preparation ProductsMANDELIC ACID HYDRAZIDE-->Methyl cyclohexylphenylglycolate-->Tetrahydroxyquinone-->Phenylacetic acid-->2,2-Dimethyl-5-phenyl-1,3-dioxolan-4-one-->SALICYLIDENE MANDELHYDRAZONE
Methylparaben Methyl METHYL A YCLOPENTYLMANDELATE Bensulfuron methyl DL-Mandelic acid Parathion-methyl α-Lipoic Acid Kresoxim-methyl Thiophanate-methyl Methyl DL-mandelate Methyl benzoate FATTY ACID METHYL ESTER MIX C8-C22 Methyl acrylate Methyl methacrylate Methyl formate Methyl acetate METSULFURON METHYL Mandelic acid
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