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O-METHYL-D-PROLINOL

O-METHYL-D-PROLINOL Basic information
Product Name:O-METHYL-D-PROLINOL
Synonyms:O-METHYL-D-PROLINOL;(R)-(-)-2-(METHOXYMETHYL)PYRROLIDINE;(R)-(+)-2-(METHOXYMETHYL)PYRROLIDINE;(R)-2-(METHOXYMETHYL)PYRROLIDINE;(R)-(-)-2-(Methoxymethyl)pyrrolidine, 98+%;D-Prolinol methyl ether;(R)-()-2-(MethoxyMethyl)pyrrolidine >=98.0% (suM of enantioMers, GC);(R)-2-(Methoxymethyl)-pyrrolidine HCl
CAS:84025-81-0
MF:C6H13NO
MW:115.17
EINECS:
Product Categories:Imidazoles, Pyrroles, Pyrazoles, Pyrrolidines;chiral;Asymmetric Synthesis;Synthetic Organic Chemistry;Chiral Compound
Mol File:84025-81-0.mol
O-METHYL-D-PROLINOL Structure
O-METHYL-D-PROLINOL Chemical Properties
alpha -2.4o (C=2% IN BENZENE)
Boiling point 61-62°C 40mm
density 0.932 g/mL at 20 °C(lit.)
refractive index n20/D 1.446
Fp 45°C
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka10.01±0.10(Predicted)
form Liquid
color Clear colorless
optical activity[α]20/D 2.4±0.3°, c = 2% in benzene
Sensitive Air Sensitive
BRN 4229755
CAS DataBase Reference84025-81-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38
Safety Statements 26-36
RIDADR UN 1993 3/PG 3
WGK Germany 3
F 3-10-34
HazardClass 3
PackingGroup III
HS Code 29339900
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
O-METHYL-D-PROLINOL Usage And Synthesis
Chemical PropertiesColorless liquid
Uses(2R)-2-(Methoxymethyl)-pyrrolidine is a useful synthetic intermediate. It can be used to prepare pyrazolo[3,4-d]pyrimidinylamino pyrrolecarboxamides for potential use as antitumor agents with reduced neutropenic side effects. It can be also used to synthesize heteroaryl pyrimidinylacetamides as A2A receptor antagonists.
O-METHYL-D-PROLINOL Preparation Products And Raw materials
N-METHYL-D-PROLINOL O-METHYL-D-PROLINOL,O-METHYL-L-PROLINOL,O-Methyl-L-prolinol, SMP (R)-(+)-1-AMINO-2-(METHOXYMETHYL)PYRROLIDINE (R,R)-(-)-2,5-BIS(METHOXYMETHYL)-PYRROLIDINE (S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE N-Methyl-L-Prolinol HCl,N-METHYL-L-PROLINOL,1-METHYL-L-PROLINOL,(S)-2-Hydroxymethyl-1-methylpyrrolidine, N-Methyl-L-prolinol N-Methyl-DL-prolinol (R)-alpha,alpha-Diphenylmethylprolinol (S)-(-)-1-AMINO-2-(METHOXYMETHYL)PYRROLIDINE
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