1-BROMO-2-METHYLNAPHTHALENE

1-BROMO-2-METHYLNAPHTHALENE Basic information
Product Name:1-BROMO-2-METHYLNAPHTHALENE
Synonyms:2-Methyl-1-bromonaphthalene;beta-Methyl-alpha-bromonaphthalene;1-BROMO-2-METHYLNAPHTHALENE;1-BroMo-2-Methylnaphthalene, GC 90%;1-broMo-2-Methylphthalene;1-BroMo-2-Methylnaphthalene technical grade, 90%;1-Bromo-2-methylnaphtalene;1-BROMO-2-METHYLNAPHTHALENE, TECH., 90%
CAS:2586-62-1
MF:C11H9Br
MW:221.09
EINECS:219-966-1
Product Categories:Aryl;C9 to C12;Naphthalene derivatives;Halogenated Hydrocarbons;Building Blocks;C9 to C12;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks
Mol File:2586-62-1.mol
1-BROMO-2-METHYLNAPHTHALENE Structure
1-BROMO-2-METHYLNAPHTHALENE Chemical Properties
Boiling point 296 °C (lit.)
density 1.418 g/mL at 25 °C (lit.)
refractive index n20/D 1.648(lit.)
Fp >230 °F
storage temp. Inert atmosphere,Room Temperature
form Liquid
color Clear yellow
Water Solubility Not miscible in water.
BRN 2042531
CAS DataBase Reference2586-62-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38-11
Safety Statements 26-36-24/25
WGK Germany 3
HS Code 29039990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
1-BROMO-2-METHYLNAPHTHALENE Usage And Synthesis
Chemical PropertiesCLEAR YELLOW LIQUID
Uses1-Bromo-2-methylnaphthalene is used as test compound in determination of halogenated hydrocarbons at trace levels by supercritical fluid chromatography-microwave-induced plasma mass spectrometry. Dynamic phosphorescence quenching of 1-bromo-2-methylnaphthalene without deoxygenation has been used for selective sensing of Cu(II) at ngm levels.
Uses1-Bromo-2-methylnaphthalene was used as test compound in determination of halogenated hydrocarbons at trace levels by supercritical fluid chromatography-microwave-induced plasma mass spectrometry.
General DescriptionDynamic phosphorescence quenching of 1-bromo-2-methylnaphthalene without deoxygenation has been used for selective sensing of Cu(II) at ngml-1 levels. It undergoes asymmetric cross-coupling reaction with its corresponding Grignard reagent using a nickel catalyst to form non-racemic 2,2′-dimethyl-1,1′-binaphthyl.
1-BROMO-2-METHYLNAPHTHALENE Preparation Products And Raw materials
Preparation Products2-METHYL-1-NAPHTHALDEHYDE 97-->1-BROMO-2-NAPHTHOIC ACID-->1-BROMO-2-(BROMOMETHYL)NAPHTHALENE
RARECHEM AL BD 0298 (1S)-1-(1-BROMO(2-NAPHTHYL))-2-METHYLPROPYLAMINE (1R)(1-BROMO(2-NAPHTHYL))CYCLOPROPYLMETHYLAMINE 1-BROMO-2-NAPHTHOIC ACID 3-AMINO-3-(1-BROMONAPHTHALEN-2-YL)-PROPIONIC ACID (1S)-1-(1-BROMO(2-NAPHTHYL))BUTYLAMINE (1R)-1-(1-BROMO(2-NAPHTHYL))PENTYLAMINE (1S)-1-(1-BROMO(2-NAPHTHYL))PROPYLAMINE RARECHEM AL BT 0198 1-BROMO-2-METHOXYMETHYLNAPHTHALENE (1-BROMO-NAPHTHALEN-2-YLMETHYL)-HYDRAZINE (1R)-1-(1-BROMO(2-NAPHTHYL))-2,2,2-TRIFLUOROETHYLAMINE (1S)-1-(1-BROMO(2-NAPHTHYL))-2,2,2-TRIFLUOROETHYLAMINE RARECHEM AL BK 0298 1-BROMO-2-(BROMOMETHYL)-6-FLUORONAPHTHALENE 1-BROMO-2-METHYLNAPHTHALENE RARECHEM AL BZ 0293 1-BROMO-2-(BROMOMETHYL)NAPHTHALENE

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