PHENYL AZIDE

PHENYL AZIDE Basic information

Product Name:	PHENYL AZIDE
Synonyms:	Azidobenzene solution ~0.5 M in 2-methyltetrahydrofuran, >=95.0% (HPLC);Azido-benzene;Benzene, triazo-;Azidobenzene solution;Phenyl azide solution;diazobenzeneimide;phenylazoimide;triazobenzene
CAS:	622-37-7
MF:	C6H5N3
MW:	119.12
EINECS:	210-730-3
Product Categories:	Aromatic Azides;Azides;Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks
Mol File:	622-37-7.mol

PHENYL AZIDE Chemical Properties

Melting point	-27.5°C
Boiling point	212.39°C (rough estimate)
density	1.0860
vapor density	73.5 at 22-24 mm
refractive index	1.5589
Fp	-12°C
storage temp.	-20°C
color	Pale-yellow oil
BRN	742248

Safety Information

Hazard Codes	F,Xn
Risk Statements	11-19-48/20/21/22-38
Safety Statements	16
RIDADR	UN 2398 3 / PGII
WGK Germany	3

MSDS Information

PHENYL AZIDE Usage And Synthesis

Uses	Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF). 2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Synthesis Reference(s)	Journal of the American Chemical Society, 89, p. 5284, 1967 DOI: 10.1021/ja00996a036 Tetrahedron Letters, 27, p. 4749, 1986 DOI: 10.1016/S0040-4039(00)85055-8
General Description	Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.
Safety Profile	Explodes when heated.Explosive or violent reactions with Lewis acids [e.g., aluminum chloride (explosive); sulfuric acid (violent)]. When heated to decomposition it emits toxic fumes of NOx.

PHENYL AZIDE Preparation Products And Raw materials

Raw materials	Hydrazine, 1-nitroso-1-phenyl--->1-Azido-2-iodobenzene solution-->1-Azido-3-iodobenzene solution-->1-azido-4-iodobenzene-->benzenediazonium
Preparation Products	1,3-bis(4-pyridylmethyl)urea-->5-Methyl-1-phenyl-1H-[1, 2, 3]triazole-4-carboxylic acid-->N-METHYL-N-PHENYLURETHANE-->N-(4-METHOXYBENZYLIDENE)ANILINE-->N-PHENYLBENZAMIDINE-->5-CHLORO-2-NITRODIPHENYLAMINE-->3-HYDRAZINOBENZOIC ACID-->4-PHENYLAZO-1-NAPHTHYLAMINE

3,3'-DIAZIDODIPHENYL SULFONE DTBPA 2-NITRO-5-AZIDOBENZOIC ACID 4-azidosalicylic acid N-hydroxysuccinimide ester N-((4-azidophenyl)thio)phthalimide SULPHO SANPAH 4-AZIDOPHENACYL BROMIDE 4-AZIDOANILINE HYDROCHLORIDE 2,6-BIS(4-AZIDOBENZYLIDENE)-4-METHYLCYCLOHEXANONE N-HYDROXYSUCCINIMIDYL-4-AZIDOBENZOATE 4-AZIDOPHENYL ISOTHIOCYANATE azapride ANB-NOS PHENYL AZIDE SADP 4-FLUORO-3-NITROPHENYL AZIDE 2,6-BIS(4-AZIDOBENZYLIDENE)CYCLOHEXANONE P-AZIDOPHENYL SULFONE

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