1-Bromoundecane

1-Bromoundecane Basic information
Product Name:1-Bromoundecane
Synonyms:1-Bromo-n-undecane;1-bromo-undecan;1-Bromundecan;1-Undecylbromide;n-Undecyl-1-bromide;N-UNDECYL BROMIDE;UNDECYL BROMIDE;undecane,1-bromo-
CAS:693-67-4
MF:C11H23Br
MW:235.2
EINECS:211-757-3
Product Categories:Alkyl;Building Blocks;Bromine Compounds;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;Alkyl Bromides;Monofunctional & alpha,omega-Bifunctional Alkanes;Monofunctional Alkanes
Mol File:693-67-4.mol
1-Bromoundecane Structure
1-Bromoundecane Chemical Properties
Melting point −9 °C(lit.)
Boiling point 137-138 °C18 mm Hg(lit.)
density 1.054 g/mL at 25 °C(lit.)
vapor density 8.2 (vs air)
refractive index n20/D 1.457(lit.)
Fp >230 °F
storage temp. Store below +30°C.
form Liquid
color Clear colorless to pale yellow
Water Solubility Insoluble in water.
BRN 1098390
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference693-67-4(CAS DataBase Reference)
EPA Substance Registry SystemUndecane, 1-bromo- (693-67-4)
Safety Information
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
TSCA Yes
HS Code 29033919
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
1-Bromoundecane Usage And Synthesis
Chemical Propertiescolourless liquid
Uses1-Bromoundecane is used in the preparation of Grignard reagent by reacting with Mg in THF (tetrahydrofuran). It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, dyes and agrochemicals.
Synthesis Reference(s)The Journal of Organic Chemistry, 45, p. 2550, 1980 DOI: 10.1021/jo01300a071
1-Bromoundecane Preparation Products And Raw materials
Preparation Products1-IODOUNDECANE-->N-UNDECYLAMINE
2-BROMOSTEARIC ACID 2,12-DIBROMOCYCLODODECANONE 9,10,12,13-TETRABROMOSTEARIC ACID 1-Bromooctadecane 1-Bromohexadecane 11-bromoundecanoyl chloride Hexabromocyclododecane 2-BROMODODECANE 1-Bromotridecane 2-BROMOHEXADECANOIC ACID Ethyl 2-bromotetradecanoate 1-Bromoicosane 2-BROMOTRIDECANE 1-Bromotetradecane 11-Bromoundecanoic acid 1,11-DIBROMOUNDECANE 2-BROMODODECANOIC ACID 1,12-Dibromododecane

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