3,3'-Dichlorobenzidine dihydrochloride

3,3'-Dichlorobenzidine dihydrochloride Basic information
Product Name:3,3'-Dichlorobenzidine dihydrochloride
Synonyms:1’-biphenyl)-4,4’-diamine,3,3’-dichloro-(dihydrochloride;1’-biphenyl]-4,4’-diamine,3,3’-dichloro-[dihydrochloride;3,3’-dichloro-benzidindihydrochloride;[1,1'-Biphenyl]-4,4'-diamine, 3,3'-dichloro-, hydrochloride (1:2);4-(4-Amino-3-chlorophenyl)-2-chloroaniline dihydrochloride;3,3'-Dichlorobenzidine·2hydrochloride;3,3'-Dichlorobenzidi;3,3'-DICHLORO-4,4'-BIPHENYLDIAMINE DIHYDROCHLORIDE
CAS:612-83-9
MF:C12H11Cl3N2
MW:289.58
EINECS:210-323-0
Product Categories:dyestuff;Biphenyl & Diphenyl ether;Intermediates of Dyes and Pigments;Organics;Aryl Amines MAK III, Category 2Chemical Class;DIA - DICMore...Close...;Alpha Sort;Amines;Analytical Standards;AromaticsChemical Class;AromaticsMethod Specific;Chemical Class;ChloroVolatiles/ Semivolatiles;D;Cancer Research;Carcinogens;DAlphabetic;Halogenated;Oeko-Tex Standard 100
Mol File:612-83-9.mol
3,3'-Dichlorobenzidine dihydrochloride Structure
3,3'-Dichlorobenzidine dihydrochloride Chemical Properties
Melting point 132~137℃
solubility Chloroform (Slightly), DMSO (Slightly, Heated), Methanol (Slightly, Heated)
form neat
Water Solubility <0.1 g/100 mL at 21.5 ºC
Stability:Stable, but may be air or light sensitive. Incompatible with strong oxidizing agents.
LogP3.76 at 20℃
CAS DataBase Reference612-83-9(CAS DataBase Reference)
EPA Substance Registry System3,3'-Dichlorobenzidine dihydrochloride (612-83-9)
Safety Information
Hazard Codes T,N
Risk Statements 45-21-43-50/53
Safety Statements 53-45-60-61
RIDADR UN 3077 9/PG 3
WGK Germany 3
RTECS DD0550000
Hazardous Substances Data612-83-9(Hazardous Substances Data)
MSDS Information
3,3'-Dichlorobenzidine dihydrochloride Usage And Synthesis
Chemical Propertiesbeige to tan powder
Chemical Properties3,3’-Dichlorobenzidine is a gray or purple crystalline solid.
Uses3,3'-Dichlorobenzidine Dihydrochloride, is structurally similar to Benzidine (B121000), and thus is considered a carcinogen. It can be used in the production of azo dyes. Dyes and metabolites, Environmental Testing
General DescriptionLight tan powder.
Air & Water ReactionsInsoluble in water.
Reactivity Profile3,3'-Dichlorobenzidine dihydrochloride reacts as a weak acid. May react vigorously with strong oxidizing agents. May generate flammable gases with strong reducing agents.
Fire HazardFlash point data for 3,3'-Dichlorobenzidine dihydrochloride are not available but 3,3'-Dichlorobenzidine dihydrochloride is probably combustible.
Flammability and ExplosibilityNonflammable
Safety ProfileConfirmed carcinogen. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits very toxic fumes of Cl and NOx.
Potential ExposureA halide-and amine-substituted aromatic compound used in the dye industry, curing agent for isocyanate terminated resins. The major uses of dichlorobenzidine are in the manufacture of pigments for printing ink, textiles, plastics, and crayons and as a curing agent for solid urethane plastics. There are no substitutes for many of its uses. Additional groups that may be at risk include workers in the printing or graphic arts professions handling the 3,3’-DCB-based azo pigments. 3,3’-DCB may be present as an impurity in the pigments, and there is some evidence that 3,3’-DCB may be metabolically liberated from the azo pigment
ShippingUN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required
IncompatibilitiesIncompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Achemical base: neutralize acids to form salts plus water with an exothermic reaction. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generatedby amines in combination with strong reducing agents such as hydrides, nitrides, alkali metals, and sulfides.
Waste DisposalIncineration (816C, 0.5 second for primary combustion; 1204C, 1.0 second for secondary combustion). The formation of elemental chlorine can be prevented through injection of steam ormethane into the combustion process. nitrogen oxides may be abated through the use of thermal or catalytic devices. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal
3,3'-Dichlorobenzidine dihydrochloride Preparation Products And Raw materials
Raw materialsSodium hydroxide-->Methanol-->Hydrazinium hydroxide solution-->Hydrazine hydrate-->1,4-Naphthoquinone
Preparation ProductsPigment Yellow 13
4-Aminobiphenyl hydrochloride 3,3',5,5'-TETRACHLOROBENZIDINE Aniline hydrochloride Biphenyl 3,3'-DICHLOROBIPHENYL 3,3',5,5'-Tetramethylbenzidine dihydrochloride Methoxyammonium chloride 3'-CHLOROBIPHENYL-4-YLAMINE 2,2'-Benzidinedisulfonic acid 3,3'-Dichlorobenzidine Pigment Yellow 81 3-CHLOROBIPHENYL 2,2',5,5'-Tetrachlorobenzidine 3,3'-Dichlorobenzidine dihydrochloride 3'-CHLORO-BIPHENYL-4-YLAMINE HYDROCHLORIDE DICHLORO BENZIDINE DI HYDROCHLORIDE (DCB) 2,3-Dichloroaniline 2-Chloro-4-methylaniline

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