ChemicalBook Product Catalog Chemical Reagents Organic reagents Borane (-)-B-METHOXYDIISOPINOCAMPHEYLBORANE

(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE

(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE Basic information
Product Name:(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE
Synonyms:(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE;(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE HYDRATE;(-)-DIISOPINOCAMPHEYLMETHOXYBORANE HYDRATE;(+)-B-Methoxydiisopinocampheylborane;(+)-B-Methoxydiisopinocampheylborane,(+)-Diisopinocampheylmethoxyborane;(-)-beta-Methoxydiisopinocampheylboranehydrate;(+)-B-methoxydiisocamphenylborane;Borinic acid, B,B-bis[(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]-, methyl ester
CAS:99438-28-5
MF:C21H37BO
MW:316.33
EINECS:
Product Categories:
Mol File:99438-28-5.mol
(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE Structure
(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE Chemical Properties
Boiling point 365.6±9.0 °C(Predicted)
density 0.95±0.1 g/cm3(Predicted)
Fp >230 °F
storage temp. 2-8°C
BRN 6370228
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
F 10-21
MSDS Information
ProviderLanguage
SigmaAldrich English
(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE Usage And Synthesis
Uses(+)?-?B-?Methoxydiisopinocamp?heylborane is a chiral catalyst used in synthetic organic chemistry such as the bacterial macrolide glycoside (-?)?-?Lyngbyaloside B which maintains antiproliferative activity.
Uses(-)-B-Methoxydiisopinocampheylborane hydrate is an intermediate used in the synthesis of homoallylic alcohol''s and several complex natural products.
UsesReactant involved in:
  • Oxidative cyclization and alkylation for synthesis of ionomycin
  • Intramolecular conjugate addition for tetrahydropyran synthesis
  • Aldol addition and Suzuki coupling reactions
  • Allylation
  • Synthesis of alkanols
(-)-B-METHOXYDIISOPINOCAMPHEYLBORANE Preparation Products And Raw materials
Preparation Products(+)-Ipc2B(allyl), 1M in dioxane
Boron Methoxydiethylborane Disiamylborane (-)-B-METHOXYDIISOPINOCAMPHEYLBORANE (1R)-(+)-TRANS-PINANE (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE
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