Tetrabutylammonium hexafluorophosphate

Tetrabutylammonium hexafluorophosphate Basic information
Product Name:Tetrabutylammonium hexafluorophosphate
Synonyms:1-Butanaminium, N,N,N-tributyl-, hexafluorophosphate(1-);tetrabutylammonium-hexafluorphosophat;ammonium hexafL;uorophosphate;TETRABUTYLAMMONIUM HEXAFLUOROPHOSPHATE;TETRABUTYLAMMONIUM HEXAFLUOROPHOSPHATE, ELECTROCHEM. GRADE;TETRA-N-BUTYLAMMONIUM HEXAFLUOROPHOSPHATE;Tetrabutylammoniumhexafluorophosphate,98%
CAS:3109-63-5
MF:C16H36F6NP
MW:387.43
EINECS:221-472-6
Product Categories:metal fluorophosphate complex;Ammonium Polyhalides, etc. (Quaternary);Quaternary Ammonium Compounds;Ammonium SaltsAnalytical Reagents;Electrochemistry;Greener Alternatives: Catalysis;Phase Transfer Catalysts;Supporting Electrolytes for Electrochemistry;Ammonium Salts
Mol File:3109-63-5.mol
Tetrabutylammonium hexafluorophosphate Structure
Tetrabutylammonium hexafluorophosphate Chemical Properties
Melting point 244-246 °C (lit.)
Boiling point 242-246 °C
storage temp. Inert atmosphere,Room Temperature
solubility acetonitrile: 0.1 g/mL, clear, colorless
form Crystalline Powder and/or Chunks
color White to off-white
Sensitive Hygroscopic
BRN 4056584
InChIInChI=1S/C16H36N.F6P/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-7(2,3,4,5)6/h5-16H2,1-4H3;/q+1;-1
InChIKeyBKBKEFQIOUYLBC-UHFFFAOYSA-N
SMILES[N+](CCCC)(CCCC)(CCCC)CCCC.[P-](F)(F)(F)(F)(F)F
CAS DataBase Reference3109-63-5(CAS DataBase Reference)
NIST Chemistry ReferenceTetrabutylammonium hexafluorophosphate(3109-63-5)
EPA Substance Registry System1-Butanaminium, N,N,N-tributyl-, hexafluorophosphate(1-) (3109-63-5)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-22
Safety Statements 26-36/37
RIDADR 1759
WGK Germany 3
Hazard Note Irritant/Hygroscopic
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29239000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Tetrabutylammonium hexafluorophosphate Usage And Synthesis
Chemical Propertiesoff-white powder
UsesTetrabutylammonium hexafluorophosphate can be used as a supporting electrolyte for the formation of cyclic disulfide moiety of 3,5-diimido-1,2-dithiolane derivatives by S-S coupling of dithioanilides.
UsesTetrabutylammonium hexafluorophosphate (TBAPF6) or TBAHP can be used:
  • As the supporting electrolyte in cyclic voltammetric studies.
  • As a reactant in the synthesis of fluorescent nanofibrous sensing films for detecting nitro-explosive vapors.

General DescriptionVisit our Sensor Applications portal to learn more.
Purification MethodsRecrystallise it from saturated EtOH/water and dry it for 10hours in a vacuum at 70o. Also recrystallise it three times from absolute EtOH and dry it for 2 days in a drying pistol under a vacuum at boiling toluene temperature [Bedard & Dahl J Am Chem Soc 108 5933 1986]. It is a stable supporting electrolyte in organic solvents [Baiser in Organic Electrochemitry M. Dekker NY p228 1973.]
Tetrabutylammonium hexafluorophosphate Preparation Products And Raw materials
Raw materialsWater-->Tetrabutylammonium bromide-->Potassium hexafluorophosphate-->Tetrabutylammonium hydroxide-->Diethyl phosphite-->Tetrabutyl ammonium chloride
Tetrabutylammonium phosphate Tetrabutylammonium hydrogen sulfate Tetrabutylammonium perchlorate Tetrabutylammonium bromide Tetrabutylammonium fluoride Sodium hexafluorophosphate Hexafluorophosphate TETRABUTYL AMMONIUM BROMIDE Salbutamol Tributylamine DOBUTAMINE Ammonium hexafluorophosphate Tetrabutylammonium hexafluorophosphate TRIETHYLAMINE PENTAHYDROFLUORIDE Lithium hexafluorophosphate DIBUTYL-PROPYL-AMINE triethylammonium fluoride Triethylamine trihydrofluoride

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