FEMA 3764

FEMA 3764 Basic information
Product Name:FEMA 3764
Synonyms:5,6,7,7a-tetrahydro-3,6-dimethyl-2(4h)-benzofuranon;5,6,7,7a-tetrahydro-3,6-dimethyl-2(4H)-Benzofuranone;MINT LACTONE;MENTHALACTONE;FEMA 3764;5,6,7,7a-tetrahydro-3,6-dimethyl-(4H)-benzofuran-2-one;MENTHALACTONE 99+%;2(4H)-Benzofuranone, 5,6,7,7a-tetrahydro-3,6-dimethyl-
CAS:13341-72-5
MF:C10H14O2
MW:166.22
EINECS:236-390-6
Product Categories:Alphabetical Listings;Flavors and Fragrances;M-N
Mol File:13341-72-5.mol
FEMA 3764 Structure
FEMA 3764 Chemical Properties
Boiling point 87-89 °C25 mm Hg(lit.)
density 1.058 g/mL at 25 °C(lit.)
FEMA 3764 | MINTLACTONE
refractive index n20/D 1.5(lit.)
Fp 176 °F
form neat
Odorat 100.00 %. sweet creamy coumarin coconut powdery tobacco spearmint
Odor Typetonka
optical activity[α]20/D 35°, neat
JECFA Number1162
LogP1.83
EPA Substance Registry System2(4H)-Benzofuranone, 5,6,7,7a-tetrahydro-3,6-dimethyl- (13341-72-5)
Safety Information
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
FEMA 3764 Usage And Synthesis
OccurrenceReported found in peppermint and pennyroyal oil, Mentha arvensi
PreparationBy asymmetric dihydroxylation reaction from intrinsically disflavored diastereoface of alkene
Aroma threshold valuesAroma characteristics at 10.0%: sweet, creamy coumarinic, slightly powdery coconut, brown vanilla-like and slightly bready.
Taste threshold valuesTaste characteristics at 20 ppm: creamy, coconut, coumarin, milky lactonic with a slight minty and anisic nuance.
Synthesis Reference(s)Tetrahedron Letters, 31, p. 6789, 1990 DOI: 10.1016/S0040-4039(00)97172-7
General DescriptionMenthalactone occurs naturally in mint. It may be contributing to its analgesic activity.
Biochem/physiol ActionsTaste at 20 ppm
FEMA 3764 Preparation Products And Raw materials
5,6,7,8-TETRAHYDROISOQUINOLINE Tetrahydrofurfuryl alcohol ETHYL 2-METHYL-3-PENTENOATE trans-3-Hexenoic acid 1-CYCLOHEXENYLACETIC ACID 2-METHYL-2-CYCLOHEXEN-1-OL FEMA 3764 Ethyl 3-hexenoate

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