GLYCIDYL ISOPROPYL ETHER

GLYCIDYL ISOPROPYL ETHER Basic information
Product Name:GLYCIDYL ISOPROPYL ETHER
Synonyms:ISOPROPOXYMETHYLOXIRANE;IPGE;1,2-epoxy-3-isopropoxy-propan;2-(Isopropoxymethyl)oxirane;3-Isopropoxy-1,2-epoxypropane;3-Isopropyloxypropylene oxide;3-isopropyloxypropyleneoxide;Isopropyl epoxypropyl ether
CAS:4016-14-2
MF:C6H12O2
MW:116.16
EINECS:223-672-9
Product Categories:Oxiranes;Simple 3-Membered Ring Compounds
Mol File:4016-14-2.mol
GLYCIDYL ISOPROPYL ETHER Structure
GLYCIDYL ISOPROPYL ETHER Chemical Properties
Boiling point 131-132 °C (lit.)
density 0.924 g/mL at 25 °C (lit.)
vapor pressure 13 hPa (25 °C)
refractive index n20/D 1.410(lit.)
Fp 92 °F
storage temp. Store below +30°C.
solubility 188g/l
form Colorless liquid
color Colorless to Almost colorless
PH7 (188g/l, H2O, 20℃)
Water Solubility 19g/L at 25℃
BRN 103028
Exposure limitsTLV-TWA 240 mg/m3 (50 ppm); TLV-STEL 360 mg/m3 (75 ppm) (ACGIH); 15-minute ceiling 50 ppm (NIOSH); IDLH 1500 ppm (NIOSH).
Stability:Stable. Flammable. Incompatible with strong oxidizing agents.
LogP0.8 at 25℃
CAS DataBase Reference4016-14-2(CAS DataBase Reference)
EPA Substance Registry SystemIsopropyl glycidyl ether (4016-14-2)
Safety Information
Hazard Codes Xi
Risk Statements 10-19-36/37/38-43
Safety Statements 16-26-36/37
RIDADR UN 3271 3/PG 3
WGK Germany 2
RTECS TZ3500000
Autoignition Temperature290 °C
HS Code 2910 90 00
HazardClass 3
PackingGroup III
Hazardous Substances Data4016-14-2(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 4200 mg/kg LD50 dermal Rabbit 9650 mg/kg
IDLA400 ppm
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
GLYCIDYL ISOPROPYL ETHER Usage And Synthesis
Chemical Propertiescolourless liquid
UsesReactive diluent for epoxy resins; stabilizer for organic compounds; chemical intermediate for synthesis of ethers and esters
UsesIsopropyl glycidyl ether (IGE) is used to sta-bilize chlorinated solvents and as a viscosityreducer of epoxy resins.
UsesGlycidyl isopropyl ether is a stabilizer of chlorinated solvents, and viscosity reducer of epoxy resins.
Production MethodsIsopropyl glycidyl ether is manufactured through the condensation of isopropyl alcohol and epichlorohydrin with subsequent dehydrochlorination with caustic to form the epoxy ring.
General DescriptionColorless liquid.
Air & Water ReactionsHighly flammable. Water soluble.
Reactivity ProfileEthers can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
HazardFlammable liquid with flash p 92F (33.33C). Skin, eye and respiratory tract irritant.
Health HazardExposure can cause mental confusion and moderate irritation of the eyes, skin, and respiratory tract. Chronic exposure can cause dermatitis and skin sensitization.
Health HazardIGE is a skin and eye irritant with lowtoxicity. Irritation in rabbits’ eyes and skincaused by 100 mg was moderate to low.In humans, frequent skin contact may causedermatitis.
Studies on rats indicated low toxicity ofthis compound with symptoms of respiratorydistress. Prolonged exposure caused ocularirritation and depression of the central ner-vous system. An increase in hemoglobin anda decrease in peritoneal fat was observed.
Fire HazardFlammable; flash point (closed cup) 33°C (92°F); vapor pressure 9.4 torr at 25°C (77°F); forms explosive mixtures with air, LEL and UEL values not reported; fire- extinguishing agent: use a water spray to extinguish fire.
GLYCIDYL ISOPROPYL ETHER Preparation Products And Raw materials
Raw materialsSodium-->Isopropyl alcohol-->Epichlorohydrin
Preparation Products1-AMINO-3-ISOPROPOXY-PROPAN-2-OL
ISOPROPYLTRIPHENYLPHOSPHONIUM IODIDE POTASSIUM I-PROPYLTRIFLUOROBORATE scirpentriol RORIDIN A T-2 TRIOL trichothecin FUSARENON X RUTAEVIN trichothecolone VERRUCAROL 1,2,3-PROPANETRIOL GLYCIDYL ETHER MUCONOMYCIN A Nomilin PICROTOXININ T-2 TETRAOL NEOSOLANIOL Limonin HT-2 TOXIN

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