Tin sulfide

Tin sulfide Basic information
Product Name:Tin sulfide
Synonyms:Herzenbergite, Stannous sulfide, Tin monosulfide;Tin(II) sulfide(SnS);STANNOUS SULFIDE;TIN MONOSULFIDE;TIN (II) SULFIDE;SnS;Tin sulfide (SnS);tinsulfide(sns)
CAS:1314-95-0
MF:SSn
MW:150.77
EINECS:215-248-7
Product Categories:Ceramic Science;Chalcogenides;Materials Science;Metal &;Metal and Ceramic Science;New Products for Materials Research and Engineering
Mol File:1314-95-0.mol
Tin sulfide Structure
Tin sulfide Chemical Properties
Melting point 882°C
Boiling point 1202.34°C (estimate)
density 5.22 g/mL at 25 °C(lit.)
form -8 Mesh
Specific Gravity5.08
Water Solubility Soluble in conc. HCl, hot conc. H{2}SO{4}.Insoluble in water.
Merck 14,8791
Solubility Product Constant (Ksp)pKsp: 25.00
Exposure limitsACGIH: TWA 2 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 2 mg/m3
LogP-2.47
CAS DataBase Reference1314-95-0(CAS DataBase Reference)
EPA Substance Registry SystemTin sulfide (SnS) (1314-95-0)
Bandgap1.07 -1.32 eV
Electronic properties2D semiconductor
color Brown/Yellow
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
TSCA Yes
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Tin sulfide Usage And Synthesis
Application

In the form of single or few-layer thin films,?exfoliated SnS?nanosheets have various applications.?These include light emitters, field effect transistors (FETs), gas sensors, photodetectors, thermoelectric and photovoltaic devices.

Synthesis

Tin sulfide?(SnS)?is manufactured using chemical vapour transport (CVT) crystallisation, with crystals having a purity in excess of 99.999%.

PreparationSynthetic?- Chemical Vapour Transport (CVT)
DescriptionTin sulfide (SnS), with a direct energy band-gap of about 1.3 eV, and a high optical absorption coefficient over 5 × 104 cm-1,?is a promising new candidate for applications in the next generation of photovoltaic solar cells. Made of earth-abundant, relatively cheap and environmentally-nontoxic elements, SnS is solution processable and stable in both alkaline and acidic conditions.
Chemical PropertiesDark-gray or black, crystalline powder. Soluble in concentrated hydrochloric acid (decomposes); insoluble in dilute acids and water.
UsesThe p-type IV-VI semiconductor tin(II) sulfide is of interest for use in optoelectronic devices. SnS is also used as a nontoxic, inexpensive component in heterojunction photovoltaic devices.
UsesPolymerization catalyst.Tin(II) sulfide is used as a polymerization catalyst. It is also used as a friction material. Further, it is used in optoelectronic device as well as a component in heterojunction photovoltaic devices.
HazardToxic material.
Flammability and ExplosibilityNotclassified
Tin sulfide Preparation Products And Raw materials
TIN SULFIDE NICKEL SULFIDE Lead(II) sulfide Zinc sulfide CADMIUM HYDROXIDE COBALT (IV) SULFIDE SILICON DISULFIDE BISMUTH SULFIDE Zinc hydroxide Bismuth trioxide ANTIMONY PENTAFLUORIDE Selenium sulfide Tin(Ⅱ) sulfide DIMETHYLTIN SULFIDE DIPHENYLTIN SULFIDE DIBUTYL TIN SULFIDE Tin sulfide dimethyldithioxodistannathiane

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