7-Ethoxy-4-methyl-2H-chromen-2-one

7-Ethoxy-4-methyl-2H-chromen-2-one Basic information
Product Name:7-Ethoxy-4-methyl-2H-chromen-2-one
Synonyms:ETHYL 4-METHYLUMBELLIFERYL ETHER;TIMTEC-BB SBB010011;7-ETHOXY-4-METHYLCOUMARIN, FOR FLUORESCE NCE;Maraniol;7-Ethoxy-4-methylcoumarin 98%;METHYL-7-ETHOXYCOUMARIN, 4-(SG);4-Methyl-7-ethoxy-2H-1-benzopyran-2-one;7-Ethoxy-4-methyl-2H-1-benzopyran-2-one
CAS:87-05-8
MF:C12H12O3
MW:204.22
EINECS:201-721-5
Product Categories:Coumarins;API intermediates
Mol File:87-05-8.mol
7-Ethoxy-4-methyl-2H-chromen-2-one Structure
7-Ethoxy-4-methyl-2H-chromen-2-one Chemical Properties
Melting point 114-116 °C (lit.)
Boiling point 351.4±37.0 °C(Predicted)
density 1.163±0.06 g/cm3(Predicted)
storage temp. -20°C Freezer, Under inert atmosphere
solubility DMF: soluble
form Solid
color White to Off-White
Odorat 100.00 %. nutty walnut
Odor Typenutty
BRN 169998
LogP2.973 (est)
CAS DataBase Reference87-05-8(CAS DataBase Reference)
NIST Chemistry Reference4-Methyl-7-ethoxycoumarin(87-05-8)
EPA Substance Registry System2H-1-Benzopyran-2-one, 7-ethoxy-4-methyl- (87-05-8)
Safety Information
Hazard Codes Xi
Safety Statements 24/25
WGK Germany 3
8
Hazard Note Irritant
TSCA Yes
HS Code 29322090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
7-Ethoxy-4-methyl-2H-chromen-2-one Usage And Synthesis
Chemical PropertiesWhite solid; walnut odor. Slightly soluble in alcohol.
UsesPerfumery, flavoring.
Uses7-Ethoxy-4-methylcoumarin was an analyte in a study of the structural characterization and retention time simulation of allergenic fragrances.
Uses7-Ethoxy-4-methylcoumarin may be used in the assay of 4-chlormethyl-7-ethoxycoumarin O-deethylase activity.
DefinitionChEBI: 7-Ethoxy-4-methyl-2H-1-benzopyran-2-one is a member of coumarins.
General Description7-Ethoxy-4-methylcoumarin (EtOMC), also known as ethyl 4-methylumbelliferyl ether, is a coumarin derivative. Its standard molar energy of combustion is ?5888.0 ± 3.2kJ·mol?1 and standard molar enthalpy of formation in the crystalline phase is ?545.4 ± 3.6kJ·mol?1.EtOMC can be prepared by reacting methyl acetoacetate with 3-ethoxyphenol in the presence of boron trifluoride dihydrate.The fluorescence quenching of EtOMC is more effective in the presence 4-hydroxy-TEMPO (4-hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl).
7-Ethoxy-4-methyl-2H-chromen-2-one Preparation Products And Raw materials
Methylparaben Methyl C8E3 Coumarin DIETHOXYMETHANE Ethylbenzene Tribenuron methyl Ethoxyquin Kresoxim-methyl Diethyl ether Ethoxy Ethyl acetate Methanol 4-Methylcumarin Ethyl acrylate Methyl acrylate 6-Methylcoumarin METSULFURON METHYL

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