ChemicalBook Product Catalog Biochemical Engineering Saccharides Monosaccharide L-Arabinopyranose

L-Arabinopyranose

L-Arabinopyranose Basic information
Product Name:L-Arabinopyranose
Synonyms:ARABITOL, L-(-)-(RG);L-ARABINOSE extrapure;(2R,3R,4S,5S)-oxane-2,3,4,5-tetrol;L-Arabinose 98%;L-(+)-Arabinose, L-arabinose;L-Arabinopyranose;l-[1-13C]arabinose;l-[2-13C]arabinose
CAS:87-72-9
MF:C5H10O5
MW:150.13
EINECS:201-767-6
Product Categories:Sugars, Carbohydrates & Glucosides;Inhibitors;Dextrins、Sugar & Carbohydrates;Carbohydrates & Derivatives;carbohydrate;Food Additives
Mol File:87-72-9.mol
L-Arabinopyranose Structure
L-Arabinopyranose Chemical Properties
Melting point 160-163 °C(lit.)
alpha 103 º (c=5, H2O)
Boiling point 191.65°C (rough estimate)
density 1.1897 (rough estimate)
refractive index 1.3920 (estimate)
storage temp. Inert atmosphere,Room Temperature
solubility Methanol (Slightly), Water (Sparingly)
pka12.26±0.70(Predicted)
form Fine Crystalline Powder
color White
Water Solubility soluble
Merck 14,761
BRN 1723085
CAS DataBase Reference87-72-9(CAS DataBase Reference)
NIST Chemistry ReferenceArabinose(L)(87-72-9)
EPA Substance Registry SystemL-Arabinopyranose (87-72-9)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 24/25-36-26
WGK Germany 3
F 3-10
TSCA Yes
HS Code 29400000
MSDS Information
ProviderLanguage
L-Arabinopyranose English
ACROS English
ALFA English
L-Arabinopyranose Usage And Synthesis
Chemical PropertiesWhite to off white crystalline powder
UsesA base component of hemicellulose and pectin, critical biopolymers.
UsesL-(+)-Arabinose is used to identify and differentiate and characterize pentose sugar isomerase. It is also used as the carbon source in microbial culture. It is involved in the bioproduction of L-ribose. It finds application in the production of savory reaction flavors. Its derivatives are used in the development of antiviral agents such as nucleoside. It acts as a base component of hemicellulose and pectin.
DefinitionChEBI: L-arabinopyranose is the six-membered ring form of L-arabinose. It has a role as an Escherichia coli metabolite and a mouse metabolite.
Purification Methodsbeta-L-(+)-Arabinose is recrystallised slowly, twice, from 80% aqueous EtOH, then dried under vacuum over P2O5. It can also be purified by heating the arabinose (200g) with glacial acetic acid (300mL) on a boiling water bath for 45minutes, cooling, filtering, washing with 95% EtOH (500mL) in four portions and drying at 56-60o over P2O5. It has been recrystallised from 5times its weight of 76% EtOH using charcoal (10g) to yield 127g, m 155-157o, [] 20D +190.6o and mutarotating to +104o (c 4, H2O). [Anderson & Sands Org Synth Coll Vol I 67 1941, Wolfrom & Christian J Am Chem Soc 48 3172 1926, Beilstein 1 IV 4217.]
L-Arabinopyranose Preparation Products And Raw materials
D-ARABINOSE-5-PHOSPHATE 3-O-β-D-Glucopyranosyl-(1→3)-α-L-arabinopyranosyl oleanolic acid 28-O-α-L-rhamnopyranosyl-(1→4)-β-D-glucopyranosyl-(1→6)-β-gulcopyranoside ARABINOIC ACID 3-O-α-L-Arabinopyranosyl oteanolic acid 28- O-β-D-glucopyrano-syl-(1 →6)- β-D-glucopyranoside α-L-Arabinofuranosyl-(1→4)-O β-D-glucurouopyranosyl-(1→3)- 3β-hudroxy-lup-20(29)-ene (R)-2-amino-4-[(2-aminopropionyl)amino]-2,4-dideoxy-L-arabinose 3T-O-Arabinopyranosyl-ent-epicatechin-(2α→7,4α→8)-catechin D-(-)-Arabinose ARABINOSE, D/L-,DL-ARABINOSE 1,2:3,4-DI-O-ISOPROPYLIDENE-ALPHA-L-ARABINOPYRANOSE 3-O-B-D-galactopyranosyl-D-arabinose D(-)Arabinose (1.01494) L-Arabinopyranose 1-O -{[α-L-Arabinopyranosyl-（l→3)]- α-L-rhamnopyranosyl-（l→ 2)- β-D-glucopyranosyl-(1→ 3)- α-L-rhamnopyranosyl-(1→6) -β-D-glucopyranosyl} hexadecanol D-ARABINOSE-1-13C, 98 ATOM % 13C L(+)Arabinose (1.01488) L-(-)-ARABITOL Arabinose paper
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