PENTYL ETHER

PENTYL ETHER Basic information
Product Name:PENTYL ETHER
Synonyms:(n-C5H11)2O;1-(Pentyloxy)pentane;1-(pentyloxy)-pentane;1,1’-oxybis-pentan;Bis(1-pentyl) ether;NSC 6571;Di-n-amyl ether (stabilised ) for synthesis;DIAMYL ETHER
CAS:693-65-2
MF:C10H22O
MW:158.28
EINECS:211-756-8
Product Categories:Solvent Packaging Options;Solvents;Amber Glass Bottles;Reagent;Solvent Bottles
Mol File:693-65-2.mol
PENTYL ETHER Structure
PENTYL ETHER Chemical Properties
Melting point −69 °C(lit.)
Boiling point 187-188 °C(lit.)
density 0.785 g/mL at 25 °C(lit.)
vapor density 5.46
vapor pressure 0.7 hPa (20 °C)
refractive index n20/D 1.412(lit.)
Fp 135 °F
storage temp. Store below +30°C.
Water Solubility Insoluble in water
form Liquid
color Colorless to Almost colorless
explosive limit2.0-8.0%(V)
Merck 14,608
BRN 1698030
Stability:Stable. Flammable. Incompatible with strong oxidising agents.
CAS DataBase Reference693-65-2(CAS DataBase Reference)
EPA Substance Registry SystemPentane, 1,1'-oxybis- (693-65-2)
Safety Information
Risk Statements 10
Safety Statements 16
RIDADR UN 3271 3/PG 3
WGK Germany 3
RTECS SC2900000
Autoignition Temperature180 °C
HS Code 2909 19 90
HazardClass 3.2
PackingGroup III
ToxicityLD50 ivn-mus: 164 mg/kg JPMSAE 67,566,78
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
PENTYL ETHER Usage And Synthesis
Chemical PropertiesCommercial diamyl ether consists principally of di-n-amyl ether and di-isoamyl ether, with small percentages of isomeric amyl ethers and diamylene. It is a colorless to light yellow liquid which is quite stable. It is insoluble in water but soluble in methanol, ethyl ether, ethyl acetate, acetone, aliphatic and aromatic hydrocarbons, fixed oils, oleic and hot stearic acids, hot paraffin and carnauba waxes, the latter two solidifying when cooled. Unlike the lower aliphatic ethers, it will not dissolve nitrocellulose when admixed with ethanol. However, a mixture of diamyl ether and 20% ethanol will dissolve ethylcellulose.
UsesDipentyl ether has been used to compose the binary mixtures with various imidazole derivatives. Solid-liquid equilibrium (SLE) of these binary mixtures have been evaluated by a dynamic method.
UsesIndustrial solvent.
General DescriptionDipentyl ether (1,1-Dipentyl ether, DPeE) is an aliphatic diether. It is formed as one of the major product during the dehydration of pentan-1-ol.
HazardNarcotic in high concentration.
Industrial usesThe commercial diamyl ether consists of a blend of di-AZ-amyl and di-iso-amyl ether, a small amount of isomeric amyl ethers and diamylene. A blend of diamyl ether and 20% ethanol will dissolve ethyl cellulose.
Safety ProfilePoison by intravenous route. Flammable liquid when exposed to heat or flame; reacts with oxidizing materials. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS
Purification MethodsRepeatedly reflux amyl ether over sodium and distil it. [Beilstein 1 IV 1643.]
4-[(4-methyl-1-piperazinyl)sulfonyl]phenyl pentyl ether 2,5-dimethylphenyl 5-(3,5-dimethyl-1H-pyrazol-4-yl)pentyl ether 2-[10-bromo-3-(butylsulfanyl)-6,7-dihydro[1,2,4]triazino[5,6-d][3,1]benzoxazepin-6-yl]phenyl pentyl ether Span 20 Cholesteryl caprylate RUBRATOXIN B Cholesteryl linoleate Ethenyl tert-pentyl ether CYMARIN 1,2-EPOXYCYCLODODECANE HECOGENIN ACETATE 4-methylphenyl 5-(1-pyrrolidinyl)pentyl ether CHOLESTERYL HEPTANOATE 4-(1H-imidazol-1-ylsulfonyl)-2-methylphenyl pentyl ether 2-chloro-5-(1H-imidazol-1-ylsulfonyl)phenyl pentyl ether Cholesteryl pelargonate CHOLESTERYL STEARATE 2-(TETRAHYDROFURFURYLOXY)TETRAHYDROPYRAN

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