ChemicalBook Product Catalog Organic Chemistry Phosphines BORANE-TRIPHENYLPHOSPHINE COMPLEX

BORANE-TRIPHENYLPHOSPHINE COMPLEX

BORANE-TRIPHENYLPHOSPHINE COMPLEX Basic information
Product Name:BORANE-TRIPHENYLPHOSPHINE COMPLEX
Synonyms:TRIPHENYLPHOSPHINE BORANE;BORANE-TRIPHENYLPHOSPHINE;BORANE-TRIPHENYLPHOSPHINE COMPLEX;Borane-triphenylphosphine complex,97%;Boran-Triphenylphosphine Complex;TriphenylphosphinBorane;Borane triphenylphosphine complex 97%;Borane triphenylphosph
CAS:2049-55-0
MF:C18H18BP
MW:276.12
EINECS:
Product Categories:B (Classes of Boron Compounds);Boranes
Mol File:2049-55-0.mol
BORANE-TRIPHENYLPHOSPHINE COMPLEX Structure
BORANE-TRIPHENYLPHOSPHINE COMPLEX Chemical Properties
Melting point 189-191 °C (lit.)
storage temp. Refrigerator
form Powder
color White
Sensitive Air & Moisture Sensitive
Stability:Stable. Incompatible with acids, oxidizing agents, acid chlorides, alcohols. May decompose on exposure to air and moisture.
CAS DataBase Reference2049-55-0(CAS DataBase Reference)
Safety Information
RIDADR UN3396
WGK Germany 3
HazardClass 4.3
PackingGroup II
HS Code 29319019
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
BORANE-TRIPHENYLPHOSPHINE COMPLEX Usage And Synthesis
Chemical Propertieswhite crystals with an unpleasant smell
UsesReactant for:
  • C-P cross coupling with aryl iodides
  • Synthesis of N-heterocyclic carbene borane complexes via Lewis base exchange
  • Catalyst-free alcoholysis to deprotect phosphane-boranes
  • Undergoing heterolytic activation
  • Deprotection via reactions with resin-supported amines
  • Insertion of overcrowded silylene into hydroboranes
BORANE-TRIPHENYLPHOSPHINE COMPLEX Preparation Products And Raw materials
TRIPHENYLBORANE-TRIPHENYLPHOSPHINE COMPLEX (R)-(-)-4,12-BIS(DI-3,5-XYLYLPHOSPHINO)[2.2]PARACYCLOPHANE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE BENZYLTRIPHENYLPHOSPHONIUM BOROHYDRIDE CHLORO(HYDROTRIS(PYRAZOL-1-YL)BORATO)BIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) ETHANOL ADDUCT BIS(TRIPHENYLPHOSPHINE)IMINIUM BOROHYDRIDE TRIS(TRIPHENYLPHOSPHINEGOLD)OXONIUM TETRAFLUOROBORATE 4-CHLOROBENZYLTRIPHENYLPHOSPHONIUM TETRAFLUOROBORATE, 98 CHLORO[HYDROTRIS(PYRAZOL-1-YL)BORATO]RUTHENIUM(II)-DICHLOROMETHANE/ETHANOL ADDUCT Phosphonium, 1,3-dithiolan-2-yltriphenyl-, tetrafluoroborate(1-) [(R)-PARAPHOS RHODIUM (NBD)]BF4 1,3-Benzodithiol-2-yltriphenyl phosphonium tetrafluoroborate BORANE-TRIPHENYLPHOSPHINE COMPLEX BENZYLTRIPHENYLPHOSPHONIUM TETRAFLUOROBORATE 1-CARBETHOXYCYCLOPROPYLTRIPHENYLPHOSPHONIUM TETRAFLUOROBORATE TETRAKIS(4-METHYLPHENYL)BORANE-TETRAPHENYLPHOSPHINE COMPLEX Bis-(triphenylphosphino)-cuprous borohydride Tetraphenylphosphonium tetrafluoroborate TETRAPHENYLPHOSPHONIUM TETRAPHENYLBORATE
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