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BROMOMETHYL ACETATE

BROMOMETHYL ACETATE Basic information
Product Name:BROMOMETHYL ACETATE
Synonyms:BROMOMETHYL ACETATE;1-Bromomethanol 1-Acetate;Acetyloxymethyl Bromide;bromo-methanoacetate;ACETOXYMETHYLBROMIDE;BROMOMETHANOLACETATE;bromomethyl ethanoate;BroMoMethyl acetate 95%
CAS:590-97-6
MF:C3H5BrO2
MW:152.97
EINECS:209-696-2
Product Categories:All Aliphatics;Aliphatics;Mutagenesis Research Chemicals;C2 to C5;Carbonyl Compounds;Esters
Mol File:590-97-6.mol
BROMOMETHYL ACETATE Structure
BROMOMETHYL ACETATE Chemical Properties
Melting point 139-140.5 °C
Boiling point 130-133 °C/750 mmHg (lit.)
density 1.56 g/mL at 25 °C (lit.)
refractive index n20/D 1.447(lit.)
RTECS AF6300200
Fp 135 °F
storage temp. 2-8°C
solubility Miscible with chloroform.
form Crystalline Powder or Powder
color White to light beige
Sensitive Moisture Sensitive
Stability:Hygroscopic, Moisture Sensitive, Volatile
CAS DataBase Reference590-97-6(CAS DataBase Reference)
EPA Substance Registry SystemMethanol, bromo-, acetate (590-97-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-45
RIDADR UN 3272 3/PG 3
WGK Germany 3
TSCA Yes
HazardClass 3.2
PackingGroup III
HS Code 29153900
MSDS Information
ProviderLanguage
SigmaAldrich English
BROMOMETHYL ACETATE Usage And Synthesis
Chemical PropertiesClear colorless to yellow liquid
UsesHas cytotoxicity and mutagenicity effects.
UsesBromomethyl acetate is involved in the preparation of optically active cyclohexene antisepsis agents. It acts as reagent in samarium diiodide-mediated conversion of ketones and aldehydes to 1,2-diacetates.
General DescriptionThe interaction of bromomethyl acetate with O(6)-alkylguanine-DNA alkyltransferase (DNA repair protein) was studied in vitro.
BROMOMETHYL ACETATE Preparation Products And Raw materials
Raw materialsMethanol, 1-(phenylthio)-, 1-acetate-->METHYLENE DIACETATE, 99-->Acetyl bromide-->Formaldehyde-->BROMOACETONE
Preparation ProductsBis(bromomethyl) ether
tert-butyl 4-((tert-butoxycarbonyl)amino)-2,6-dichloronicotinate Di-tert-Butyl 5-bromopyridin-2-ylimidodicarbonate 2-Mehtyl-6-[bis(tert-butoxycarbonyl)aMino]-4-chloropyriMidine Phenyl bromoacetate IMINODICARBOXYLIC ACID TERT-BUTYL METHYL ESTER ETHYL METHYL ETHER Ethanol 3-Bromophthalide DIBROMODIBUTENDIOL DIACETATE Formic acid 2-BROMOMETHYL ACETATE BROMOMETHYL ACETATE Acetic acid Methyl 2-bis-(bromomethyl)-acetate Dimethyl ether Methyl formate 2-Pyrrolidinecarboxylic acid, 1-hydroxy-, 1,2-dibromoethyl ester, benz oate, L- Methyl acetate
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