(-)-MENTHYL CHLOROFORMATE

(-)-MENTHYL CHLOROFORMATE Basic information

Product Name:	(-)-MENTHYL CHLOROFORMATE
Synonyms:	(-)-MENTHYL CHLOROFORMATE;(-)-CHLOROFORMYLOXY-P-MENTHANE;(-)-(1R)-Menthyl chloroformate (99% EE/GLC);(1R)-(-)-MENTHYL CHLOROFORMATE 95+%;L-MenthylChloroformate;(1R,2S,5R)-(-)-MENTHYLCHLOROFORMATE;(-)-(1R)-MENTHYL CHLOROFORMATE;(1R)-(-)-MENTHYL CHLOROFORMATE
CAS:	14602-86-9
MF:	C11H19ClO2
MW:	218.72
EINECS:	672-624-7
Product Categories:	CHLOROFORMATES;chiral;Biochemistry;for Resolution of Alcohols & Thiols;for Resolution of Bases;Monocyclic Monoterpenes;Optical Resolution;Synthetic Organic Chemistry;Terpenes
Mol File:	14602-86-9.mol

(-)-MENTHYL CHLOROFORMATE Chemical Properties

Boiling point	108-109 °C11 mm Hg(lit.)
density	1.031 g/mL at 20 °C(lit.)
vapor pressure	0.01 psi ( 20 °C)
refractive index	n20/D 1.459
Fp	158 °F
storage temp.	2-8°C
solubility	Chloroform (Sparingly), Methanol (Sparingly)
form	clear liquid
color	Colorless to Almost colorless
optical activity	[α]20/D 83°, c = 1 in chloroform
Sensitive	Moisture Sensitive
BRN	2414686
CAS DataBase Reference	14602-86-9(CAS DataBase Reference)

Safety Information

Hazard Codes	T,N
Risk Statements	23-34-51/53
Safety Statements	26-36/37/39-45-61
RIDADR	UN 3277 6.1/PG 2
WGK Germany	3
F	10-19-21
HS Code	2915.90.5010
HazardClass	6.1
PackingGroup	II

MSDS Information

Provider	Language
SigmaAldrich	English
ALFA	English

(-)-MENTHYL CHLOROFORMATE Usage And Synthesis

Uses	Readily forms a chloroimidodicarbonate which asymmetrically chlorinates silyl enol ethers under mild conditions and in good yields.

(-)-MENTHYL CHLOROFORMATE Preparation Products And Raw materials

Raw materials	L-Menthol
Preparation Products	Isobutyric acid-->Mercaptoacetic acid-->Ethyl 5-[3-(4,6-dimethoxy pyrimidyl-2-yl)ureido]methylpyrazolyl-4-carboxylic ester-->FENOTHIOCARB-->2-Naphthalenethiol-->Benzyl formate-->Alclometasone Dipropionate-->TIADINIL-->BENFURACARB-->biodegrddable finishing agent for fabric-->Butyl formate-->1,2-Pentanediol-->Geranyl formate-->azafenidin-->OCTYL FORMATE-->cis-3-Hexenyl formate

Diisopropyl chlorophosphate CHLOROFORMIC ACID N-OCTYL ESTER 2-Ethylhexyl chloroformate DL-Menthol CHLOROMETHYL ISO-PROPYL ETHER Chloromethyl methyl ether CHLOROMETHYL PROPYL ETHER Isobutyl formate P-MENTHANE Z-Menthyl chloroformate 2,5-DIMETHYLCYCLOHEXANOL CHLOROMETHYL OCTYL ETHER Iodopropynyl butylcarbamate CHLOROMETHYL BUTYL ETHER Heptyl chloroformate 2-Methylcyclohexanol 2-ETHYLCYCLOHEXANOL CHLOROMETHYL CYCLOHEXYL ETHER

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