ChemicalBook Product Catalog Organic Chemistry Organometallic compounds 4-ETHOXY-4-OXOBUTYLZINC BROMIDE

4-ETHOXY-4-OXOBUTYLZINC BROMIDE

4-ETHOXY-4-OXOBUTYLZINC BROMIDE Basic information
Product Name:4-ETHOXY-4-OXOBUTYLZINC BROMIDE
Synonyms:3-(Ethoxycarbonyl)propylzinc bromide;3-(Ethoxycarbonyl)propylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles;(4-ethoxy-4-oxobutyl)zinc(II) broMide;4-Ethoxy-4-oxobutylzinc broMide solution 0.5 M in THF;4-ETHOXY-4-OXOBUTYLZINC BROMIDE, 0.5MSOL UTION IN TETRAHYDROFURAN;4-ETHOXY-4-OXOBUTYLZINC BROMIDE;4-ethoxy-4-oxobutylzinc bromide solution;4-Ethoxy-4-oxobutylzinc bromide solution 0.5 in THF
CAS:131379-39-0
MF:C6H11BrO2Zn
MW:260.44
EINECS:
Product Categories:Alkyl;Organozinc Halides;Reike and Organozinc Reagents
Mol File:131379-39-0.mol
4-ETHOXY-4-OXOBUTYLZINC BROMIDE Structure
4-ETHOXY-4-OXOBUTYLZINC BROMIDE Chemical Properties
density 0.976 g/mL at 25 °C
Fp 1 °F
storage temp. 2-8°C
Water Solubility Reacts with water.
Sensitive Air Sensitive
Exposure limitsACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
Safety Information
Hazard Codes F,Xn
Risk Statements 14-19-22-36/37/38-40-36/37
Safety Statements 16-26-33-36/37/39-45-36/37
RIDADR UN 3399 4.3/PG 2
WGK Germany 1
HazardClass 4.3
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
4-ETHOXY-4-OXOBUTYLZINC BROMIDE Usage And Synthesis
Uses4-Ethoxy-4-oxobutylzinc bromide can be used:
  • As an intermediate in one of the key synthetic steps for the preparation of acrylic acid derivatives as EP3 receptor antagonists.
  • As an intermediate in the final step of the total synthesis of a natural product mucosin.
  • As a substrate in the synthesis of multi-substituted haloalkenes by reacting with 1-haloalkenes via Negishi cross-coupling reaction.

4-ETHOXY-4-OXOBUTYLZINC BROMIDE Preparation Products And Raw materials
6-ETHOXY-6-OXOHEXYLZINC BROMIDE 5-ETHOXY-5-OXOPENTYLZINC BROMIDE 4-BIPHENYLZINC BROMIDE (1,3-DIOXAN-2-YLETHYL)ZINC BROMIDE 1-METHYLBUTYLZINC BROMIDE 2-CHLOROPHENYLZINC IODIDE PHENYLZINC BROMIDE 1-METHYLHEXYLZINC BROMIDE 4-CHLOROBUTYLZINC BROMIDE (1,3-DIOXOLAN-2-YLETHYL)ZINC BROMIDE CYCLOPROPYLZINC BROMIDE SOLUTION 0.5M I& 1-HEXYLZINC BROMIDE 5-(1,3-DIOXOLAN-2-YL)-2-THIENYLZINC BROMIDE 2 3 4 5 6-PENTAFLUOROBENZYLZINC BROMIDE& BUTYLZINC BROMIDE 4-ETHOXY-4-OXOBUTYLZINC BROMIDE N-PROPYLZINC BROMIDE 4-TERT-BUTOXY-4-OXOBUTYLZINC BROMIDE
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