TRANS-2-(4-CHLOROPHENYL)VINYLBORONIC ACID

TRANS-2-(4-CHLOROPHENYL)VINYLBORONIC ACID Basic information
Product Name:TRANS-2-(4-CHLOROPHENYL)VINYLBORONIC ACID
Synonyms:TRANS-2-(4-CHLOROPHENYL)VINYLBORONIC ACID;RARECHEM AL BA 0169;TRANS-2-(4-CHLOROPHENYL)VINYLBORONIC ACI;TRANS-2-(4-CHLORPHENYL)VINYLBORONIC ACID;trans-2-(4-Chlorophenyl)ethenylboronic acid;Boronic acid, [(1E)-2-(4-chlorophenyl)ethenyl]-;(4-Chlorostyryl)boronic acid;[(Z)-2-(4-chlorophenyl)ethenyl]boronic acid
CAS:154230-29-2
MF:C8H8BClO2
MW:182.41
EINECS:
Product Categories:Alkenyl Boronic Acids;Boronic Acids;Alkenyl;Boronic Acids and Derivatives;Chemical Synthesis;Organometallic Reagents;Boronic Acids;Boronic Acids and Derivatives
Mol File:154230-29-2.mol
TRANS-2-(4-CHLOROPHENYL)VINYLBORONIC ACID Structure
TRANS-2-(4-CHLOROPHENYL)VINYLBORONIC ACID Chemical Properties
Melting point 165 °C (dec.)(lit.)
Boiling point 356.7±44.0 °C(Predicted)
density 1.277±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka9.55±0.43(Predicted)
form Crystalline Powder
color White to off-white
CAS DataBase Reference154230-29-2(CAS DataBase Reference)
Safety Information
WGK Germany 3
HS Code 29310099
MSDS Information
ProviderLanguage
SigmaAldrich English
TRANS-2-(4-CHLOROPHENYL)VINYLBORONIC ACID Usage And Synthesis
UsesReactant involved in:• ;Synthesis of biarylketones and phthalides1• ;Trifluoromethylation2• ;Asymmetrical Michael addition for preparation of chromanes3• ;Cobalt-catalyzed coupling to vinyl nitrogen containing heteroaromatic compounds4• ;1,2 and 1,4-Addition reactions with o-hydroxycinnamaldehydes5• ;Petasis reactions6
UsesReactant involved in:
  • Synthesis of biarylketones and phthalides
  • Trifluoromethylation
  • Asymmetrical Michael addition for preparation of chromanes
  • Cobalt-catalyzed coupling to vinyl nitrogen containing heteroaromatic compounds
  • 1,2 and 1,4-Addition reactions with o-hydroxycinnamaldehydes
  • Petasis reactions
TRANS-2-(4-CHLOROPHENYL)VINYLBORONIC ACID Preparation Products And Raw materials
Chlorphenesin E-2-(3,5-DIMETHOXYPHENYL)VINYLBORONIC ACID PINACOL ESTER 2-PHENYLVINYLBORONIC ACID TRANS-2-(4-CHLOROPHENYL)VINYLBORONIC ACID TRANS-1-PROPEN-1-YLBORONIC ACID TRANS-2-(3-CHLOROPHENYL)VINYLBORONIC ACID PINACOL ESTER

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