3-Methylbenzyl bromide

3-Methylbenzyl bromide Basic information

Product Name:	3-Methylbenzyl bromide
Synonyms:	1-(bromomethyl)-3-methyl-benzen;alpha-bromo-m-xylen;Benzene, 1-(bromomethyl)-3-methyl-;bromo-xylene;m-(Bromomethyl)toluene;m-Xylene, alpha-bromo-;omega-bromo-m-xylene;1-(BROMOMETHYL)-3-METHYLBENZENE
CAS:	620-13-3
MF:	C8H9Br
MW:	185.06
EINECS:	210-625-2
Product Categories:	Aryl;Building Blocks;C8;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks;Methyl Halides;Phenyls & Phenyl-Het;Benzyl;Methyl Halides;Phenyls & Phenyl-Het
Mol File:	620-13-3.mol

3-Methylbenzyl bromide Chemical Properties

Melting point	-20.49°C (estimate)
Boiling point	185 °C340 mm Hg(lit.)
density	1.37 g/mL at 25 °C(lit.)
refractive index	n20/D 1.566(lit.)
Fp	180 °F
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
solubility	Chloroform (Sparingly), Methanol (Slightly)
form	Liquid
color	Clear colorless to light yellow
Water Solubility	practically insoluble
Merck	14,10090
BRN	2076425
CAS DataBase Reference	620-13-3(CAS DataBase Reference)
NIST Chemistry Reference	1-Bromomethyl-3-methylbenzene(620-13-3)
EPA Substance Registry System	Benzene, 1-(bromomethyl)-3-methyl- (620-13-3)

Safety Information

Hazard Codes	C
Risk Statements	20/22-34-20/21/22
Safety Statements	26-27-36/37/39-45-7/9
RIDADR	UN 1701 6.1/PG 2
WGK Germany	3
RTECS	CY9039200
Hazard Note	Corrosive
TSCA	Yes
HazardClass	6.1
PackingGroup	II
HS Code	29039990
Hazardous Substances Data	620-13-3(Hazardous Substances Data)

MSDS Information

Provider	Language
m-Xylyl bromide	English
ACROS	English
SigmaAldrich	English
ALFA	English

3-Methylbenzyl bromide Usage And Synthesis

Chemical Properties	clear colorless to light yellow liquid
Uses	3-(Bromomethyl)toluene is used to prepare TNF-??a converting enzyme (TACE) converting enzyme inhibitors. It is also used to synthesize chromen-4-ones as DNA-dependent protein kinase inhibitors.

3-Methylbenzyl bromide Preparation Products And Raw materials

Raw materials	3-Methyl-1-dibromomethylbenzene-->6-Oxatricyclo[3.2.1.02,7]octan-8-one-->Cobalt, bis[[2,3-butanedione di(oximato-κN)](1-)][(3-methylphenyl)methyl](pyridine)-, (OC-6-12)- (9CI)-->1,3-Bis(bromomethyl)benzene-->1-bromo-2-(bromomethyl)-4-methylbenzene-->Bromotrichloromethane-->3-Methylbenzyl alcohol-->Carbon tetrabromide-->P-XYLENE-->m-Tolualdehyde-->m-Xylene
Preparation Products	M-TOLYL-METHANESULFONYL CHLORIDE-->2,4-Dimethylbromobenzene-->METHYL 3-METHYLPHENYLACETATE-->4,4,5,5-tetramethyl-2-(4-((3-methylbenzyl)oxy)phenyl)-1,3,2-dioxaborolane

Rocuronium bromide 1,3-bis(1,2-dibromoethyl)benzene Musk xylene Isopropyl-α-[2-methylhydrazino]-p-toluamide Phenethyl alcohol 3-Chlorobenzyl chloride BRETYLIUM TOSYLATE 2-(BROMOMETHYL)ANTHRAQUINONE 3-(BROMOMETHYL)BENZYLTRIPHENYLPHOSPHONIUM BROMIDE Sodium bromate 2-Methylbenzyl chloride Benzyl bromide 3-Methylbenzyl bromide Ethidium bromide Allyl bromide Methyl bromide 1,3-Bis(bromomethyl)benzene Diethylstilbestrol

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