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| | O-DIPHENYLPHOSPHINYLHYDROXYLAMINE Basic information |
| Product Name: | O-DIPHENYLPHOSPHINYLHYDROXYLAMINE | | Synonyms: | O-DIPHENYLPHOSPHINYLHYDROXYLAMINE;O-(diphenylphosphoryl)hydroxylaMine;TwoPhenylphosphonichydroxylaMine;diphenylphosphinate;O-(Diphenylphosphinyl)hydroxylamine;aMino diphenylphosphinate;(AMinooxy)diphenylphosphine oxide;HydroxylaMine, O-(diphenylphosphinyl)- | | CAS: | 72804-96-7 | | MF: | C12H12NO2P | | MW: | 233.2 | | EINECS: | | | Product Categories: | | | Mol File: | 72804-96-7.mol |  |
| | O-DIPHENYLPHOSPHINYLHYDROXYLAMINE Chemical Properties |
| Melting point | >140℃ (decomposition) | | Boiling point | 368.0±25.0 °C(Predicted) | | density | 1.25±0.1 g/cm3(Predicted) | | storage temp. | 2-8°C | | solubility | DMSO (Slightly), Methanol (Very Slightly, Sonicated) | | pka | -1.65±0.70(Predicted) | | form | solid | | color | white | | InChI | InChI=1S/C12H12NO2P/c13-15-16(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H,13H2 | | InChIKey | SJECIYLGISUNRO-UHFFFAOYSA-N | | SMILES | P(C1=CC=CC=C1)(C1=CC=CC=C1)(ON)=O |
| | O-DIPHENYLPHOSPHINYLHYDROXYLAMINE Usage And Synthesis |
| Chemical Properties | Light yellow or white powder solid | | Uses | Efficient reagent for direct conversion of aldehydes to nitriles in the presence of alcohol, ketone, ester, or amine functionality. | | Uses | O-Diphenylphosphinylhydroxylamine is a versatile reactant used in the synthetic preparation of various products such as trans-acylaziridines and aldohydrazones. | | Synthesis Reference(s) | Tetrahedron Letters, 23, p. 3835, 1982 DOI: 10.1016/S0040-4039(00)87720-5 | | General Description | O-(Diphenylphosphinyl)hydroxylamine is a general reagent for electrophilic C-amination, which aminates a variety of stable carbanions and Grignard reagents. |
| | O-DIPHENYLPHOSPHINYLHYDROXYLAMINE Preparation Products And Raw materials |
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