CYCLOHEPTENE

CYCLOHEPTENE Basic information
Product Name:CYCLOHEPTENE
Synonyms:CYCLOHEPTENE;SUBERYLENE;SUBERENE;(Z)-Cycloheptene;1-Cycloheptene;Cycloheptene(Z);Cyclohepten;(Z)-1-Cycloheptene
CAS:628-92-2
MF:C7H12
MW:96.17
EINECS:211-060-4
Product Categories:Alkenes;Cyclic;Organic Building Blocks
Mol File:628-92-2.mol
CYCLOHEPTENE Structure
CYCLOHEPTENE Chemical Properties
Melting point -56 °C
Boiling point 112-114.7 °C (lit.)
density 0.824 g/mL at 25 °C (lit.)
refractive index n20/D 1.458(lit.)
Fp 20 °F
storage temp. Flammables area
form Liquid
color Clear colorless
Water Solubility Insoluble in water.
BRN 1900884
CAS DataBase Reference628-92-2(CAS DataBase Reference)
EPA Substance Registry SystemCycloheptene (628-92-2)
Safety Information
Hazard Codes F
Risk Statements 11
Safety Statements 16-29-33
RIDADR UN 2242 3/PG 2
WGK Germany 1
HazardClass 3
PackingGroup II
HS Code 29038900
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
CYCLOHEPTENE Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS LIQUID
UsesCycloheptene was used in one-pot synthesis of 1,2/3-triols from the allylichydroperoxides catalyzed by zeolite-confined osmium(0) nanoclusters. It is a raw material in organic chemistry and a monomer in polymer synthesis. Copper (1) triflate catalyzes the photodimerization of the simple nonconjugated unstrained olefins, cyclopentene, cyclohexene, and cycloheptene, but not cyclooctene or acyclic olefins.
Synthesis Reference(s)The Journal of Organic Chemistry, 41, p. 896, 1976 DOI: 10.1021/jo00867a038
General DescriptionA colorless oily liquid. Insoluble in water and less dense than water. Flash point 70°F. Vapors heavier than air. Inhalation of high concentrations may have a narcotic effect. Used to make other chemicals.
Air & Water ReactionsHighly flammable. Insoluble in water.
Reactivity ProfileCYCLOHEPTENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions.
Health HazardInhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
CYCLOHEPTENE Preparation Products And Raw materials
Raw materialsTropolone
Preparation ProductsBipariden-->Cycloheptanol-->1,8-NONADIENE-->CYCLOHEPTANE-->2-Cyclohepten-1-one-->1-METHYL-1-CYCLOHEXENE-->Biphenyl
PHORBOL 12-MYRISTATE 13-ACETATE 4-O-METHYL ETHER, 4BETA PHORBOL 13-ACETATE PHORBOL-12-MONOMYRISTATE 2-Cyclohepten-1-one VETIVEROL PHORBOL 12,13-DIACETATE 20-OXO-20-DEOXYPHORBOL 12,13-DIBUTYRATE 1-METHYL-1-CYCLOHEPTENE PHORBOL 12,13-DIBENZOATE PHORBOL 12-MONOACETATE, 4BETA (-)-ISOLEDENE PHORBOL, 20-OXO-20-DEOXY 12-MYRISTATE 13-ACETATE, 4BETA 2-CARENE (+)-LEDENE (-)-THUJOPSEN 4ALPHA-PHORBOL 4ALPHA-PHORBOL 12,13-DIDECANOATE PHORBOL 13,20-DIACETATE

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