4-Chlorophenoxyacetic acid

4-Chlorophenoxyacetic acid Basic information
Product Name:4-Chlorophenoxyacetic acid
Synonyms:2-(4-Chloro-phenoxy)acetic acid;RARECHEM AL BO 0389;P-CHLOROPHENOXYACETIC ACID;p-Monochlorophenoxy acetic acid;(2-chlorophenoxy)ethanoicacid;kyselina4-chlorfenoxyoctova;Marks 4-cpa;marks4-cpa
CAS:122-88-3
MF:C8H7ClO3
MW:186.59
EINECS:204-581-3
Product Categories:Organic acids;Phenoxyacetic Acids and Alcohols (substituted);PLANT GROWTH REGULATOR;Auxins;Biochemistry;Plant Growth Regulators;Pharmaceutical Raw Materials
Mol File:122-88-3.mol
4-Chlorophenoxyacetic acid Structure
4-Chlorophenoxyacetic acid Chemical Properties
Melting point 157-159 °C
Boiling point 266.91°C (rough estimate)
density 1.3245 (rough estimate)
refractive index 1.5250 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility 957mg/l
pkapK1: 3.10 (25°C)
form crystalline
color White to light beige
Water Solubility 848mg/L(25 ºC)
BRN 1211804
LogP2.250
CAS DataBase Reference122-88-3(CAS DataBase Reference)
NIST Chemistry Reference4-Chlorophenoxyacetic acid(122-88-3)
EPA Substance Registry System4-Chlorophenoxyacetic acid (122-88-3)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 22-R22
Safety Statements 22-24/25
RIDADR 2811
WGK Germany 1
RTECS AG0175000
21
TSCA Yes
HazardClass IRRITANT
HS Code 29189090
Hazardous Substances Data122-88-3(Hazardous Substances Data)
ToxicityLD50 oral in rat: 850mg/kg
MSDS Information
ProviderLanguage
4-CPA English
SigmaAldrich English
ACROS English
ALFA English
4-Chlorophenoxyacetic acid Usage And Synthesis
Chemical Propertieswhite to light beige powder
Uses2-(4-Chlorophenoxy)acetic Acid is used in the synthesis of a new class of hypoxia-inducible factor-1 inhibitors.
Uses4-chlorophenoxy acetic acid (4-CPA), a chlorine derivative of phenoxyacetic acid (PA), is a plant growth regulator used as a herbicide.
DefinitionChEBI: A chlorophenoxyacetic acid that is phenoxyacetic acid carrying a chloro substituent at position 4.
General Description4-Chlorophenoxyacetic acid is a herbicide. Degradation of 4-chlorophenoxyacetic acid in aqueous medium by advanced electrochemical oxidation processes, using an undivided cell containing a Pt anode has been reported.
HazardModerately toxic; mutagen.
Biochem/physiol Actions4-Chlorophenoxyacetic acid is a synthetic auxin, that is used to induce parthenocarpic ovary growth on flowers of wild type plants.
Safety ProfileModerately toxic by ingestion and intraperitoneal routes. Human mutation data reported. When heated to decomposition it emits toxic fumes of Cl-.
Purification MethodsCrystallise the acid from EtOH. It is a plant growth substance and a herbicide. [Beilstein 6 IV 845.]
2.4.5-T ISOPROPYL ESTER 2-(4-CHLOROPHENOXY) PROPIONIC ACID 2-(4-Chlorophenoxy)-2-methylpropionic acid Bis(2,4,6-trichlorophenyl)ethanedioate phenoxybenzamine ​4-Chlorophenoxyacetic acid sodium salt 2,4-D-METHYL ESTER 2-Chlorophenylacetic acid 2-(2,4,5-TRICHLOROPHENOXY)PROPIONIC ACID 3,4-D Clofibrate MCPA SODIUM 2,4,5-Trichlorophenoxyacetic acid Dichlorprop BIS(4-CHLOROPHENOXY)ACETIC ACID 2,4-Dichlorophenoxyacetic acid Meclofenoxate hydrochloride Phenylacetic acid

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