(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE

(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Basic information
Reaction
Product Name:(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE
Synonyms:(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE;(S,S)-ME-BPE;(-)-1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane, Kanata purity;(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane,98+%(S,S)-Me-BPE;1,2-Bis[(2S,5S)-2,5-diMethyl-1-phospholanyl]ethane, 97+%;(-)-1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane, 97% (S,S-Me-BPE);(-)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)ethane (S,S)-Me-BPE;1,2-Bis[(2S,5S)-2,5-dimethyl-1-phospholanyl]ethane
CAS:136779-26-5
MF:C14H28P2
MW:258.32
EINECS:
Product Categories:organophosphine ligand
Mol File:136779-26-5.mol
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Structure
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Chemical Properties
Boiling point 64-67 °C0.06 mm Hg
alpha -263° ±3° (c 1, hexane)
density 0.938 g/mL at 25 °C
refractive index n20/D 1.535
form liquid
color colorless to pale-yellow
Sensitive Air Sensitive
Safety Information
Hazard Codes F
Risk Statements 11-17
Safety Statements 24/25
RIDADR UN 2845 4.2/PG 1
WGK Germany 3
HazardClass 4.2
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Usage And Synthesis
ReactionThe DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Reactions of 136779-26-5
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE Preparation Products And Raw materials
(+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE,(+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane,98+%(R,R)-Me-BPE (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE (+)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)trifluoromethanesulfonate (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (-)-1,2-BIS((2S,5S)-2,5-DIETHYLPHOSPHOLANO)ETHANE (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM(I)TRIFLUOROMETHANESULFONATE (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE 1,2-BIS((2R,5R)-2,5-DIISOPROPYLPHOSPHOLANO)ETHANE (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)trifluoromethanesulfonate (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

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