CHLOROTRIS(TRIPHENYLPHOSPHINE)COBALT(I)

CHLOROTRIS(TRIPHENYLPHOSPHINE)COBALT(I) Basic information
Reaction
Product Name:CHLOROTRIS(TRIPHENYLPHOSPHINE)COBALT(I)
Synonyms:CHLOROTRIS(TRIPHENYLPHOSPHINE)COBALT(I);cobalt(I) tris(triphenylphosphine) chloride;Chlorotris(triphenylphosphine)cobalt(I), min. 98%;Chlorotris(triphenylphosphine)cobalt(I),Min.98%;Chlorotris(triphenylphosphine)cobalt(I),98% (PPh3)3CoCl;Tris(triphenylphosphine)cobalt chloride;Chlorotris(triphenylphosphine)cobalt(I);Cobalt,triphenylphosphane,chloride
CAS:26305-75-9
MF:C54H45ClCoP3
MW:881.24
EINECS:
Product Categories:Co;metal-phosphine complex;Catalysis and Inorganic Chemistry;Chemical Synthesis;Cobalt
Mol File:26305-75-9.mol
CHLOROTRIS(TRIPHENYLPHOSPHINE)COBALT(I) Structure
CHLOROTRIS(TRIPHENYLPHOSPHINE)COBALT(I) Chemical Properties
Melting point 135-139 °C (dec.)(lit.)
storage temp. Inert atmosphere,Room Temperature
form Powder
color brown
Water Solubility Insoluble in water.
Sensitive Air & Moisture Sensitive
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22
Safety Statements 22-26-28-37/39
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
CHLOROTRIS(TRIPHENYLPHOSPHINE)COBALT(I) Usage And Synthesis
Reaction
  1. Cobalt(I)-catalyzed, steroselective olefination of alkylzinc reagents with aryl aldehydes.
  2. Reagent for the reductive radical dimerization of 3-haloindoline derivatives.
  3. Cobalt-catalyzed, asymmetric addition of silylacetylene to 1,1-disubstituted allenes.
Reactions of 26305-75-9
UsesA stoichiometric reducing agent that is used in the radical dimerization of halogenated organic molecules.
UsesA stoichiometric reducing agent employed in the radical dimerization of halogenated organic molecules.
CHLOROTRIS(TRIPHENYLPHOSPHINE)COBALT(I) Preparation Products And Raw materials
Cobaltouschloridepaper Tris(triphenylphosphine)rhodiu cobalt trichloride Ferric chloride Cobalt chloride

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