Phenyltrimethoxysilane

Phenyltrimethoxysilane Basic information

Product Name:	Phenyltrimethoxysilane
Synonyms:	Benzene, (triMethoxysilyl)-;Trimethoxyphenylsilane >=94%;Trimethoxyphenylsilane deposition grade, 98%;A 153;CP0330;phenyltrimethoxy-silan;Silane, phenyltrimethoxy-;PhenyltriMethoxysilane, 85% 250ML
CAS:	2996-92-1
MF:	C9H14O3Si
MW:	198.29
EINECS:	221-066-9
Product Categories:	silane;organosilicon compounds;Functional Materials;Si (Classes of Silicon Compounds);Silane Coupling Agents;Silane Coupling Agents (Intermediates);Si-O Compounds;Trialkoxysilanes;Phenyl Silanes
Mol File:	2996-92-1.mol

Phenyltrimethoxysilane Chemical Properties

Melting point	-25°C
Boiling point	233 °C(lit.)
density	1.062 g/mL at 25 °C(lit.)
vapor pressure	0-12790Pa at 20-25℃
refractive index	n20/D 1.468(lit.)
Fp	99 °F
storage temp.	Inert atmosphere,2-8°C
form	liquid
Specific Gravity	1.064
color	colorless
Water Solubility	Reacts with water.
Hydrolytic Sensitivity	7: reacts slowly with moisture/water
Sensitive	Moisture Sensitive
BRN	2937896
LogP	-0.74-2 at 22℃
CAS DataBase Reference	2996-92-1(CAS DataBase Reference)
NIST Chemistry Reference	Silane, trimethoxyphenyl-(2996-92-1)
EPA Substance Registry System	Silane, trimethoxyphenyl- (2996-92-1)

Safety Information

Hazard Codes	T,Xi,Xn
Risk Statements	10-36/37/38-68/20/21/22-20/21/22-14
Safety Statements	7-16-26-36/37-45-37/39-36
RIDADR	UN 1992 3/PG 3
WGK Germany	3
RTECS	VV5252000
F	10-21
TSCA	Yes
HazardClass	3.2
PackingGroup	III
HS Code	29319090

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

Phenyltrimethoxysilane Usage And Synthesis

Chemical Properties	Colorless transparent liquid
Uses	An organosilicate compound for nanoelectronics and material science research.
Uses	Phenyltrimethoxysilane is used for nanoelectronics and material science research. It is used as crosslinking agent for silicone resin and to produce polymer organic silicon compound.
Uses	TMPS can also be used in the preparation of polytrimethoxyphenylsilane (PTMS) that facilitates the removal of graphene after chemical vapor deposition (CVD). Molecularly imprinted sol gels can be synthesized by using TMPS for the fabrication of localized surface plasmon resonance (LSPR).
General Description	Trimethoxyphenylsilane (TMPS) is an organotrialkoxysilane that is used as a functional monomer in the sol-gel processing.
Flammability and Explosibility	Flammable
Purification Methods	Fractionate it through an efficient column but note that it forms an azeotrope with MeOH which is a likely impurity. [Kantor J Am Chem Soc 75 2712 1953 Beilstein 16 IV 1556.]

Phenyltrimethoxysilane Preparation Products And Raw materials

Preparation Products

4-Biphenylacetic acid-->2-Biphenylcarboxylic acid-->(4-TERT-BUTYL-PHENYL)-PHENYL-AMINE-->2-METHOXYBIPHENYL-->4-Methylbenzhydrol-->2-Chloro-N-phenylacetamide-->Phenyltris(trimethylsiloxy)silane-->2-Biphenylcarboxaldehyde-->Diethyl phenylmalonate-->3-AMINOBIPHENYL-->Phenyltris(dimethylsiloxy)silane

3,5,8-Trioxa-4-siladecanoic acid, 2,6-bis(2-methylphenyl)-4-(2-ethoxy- 1-(2-methylphenyl)-2-oxoethoxy)-7-oxo-4-phenyl-, ethyl ester P-TOLYLTRIMETHOXYSILANE (4-ethenylphenyl) trimethoxy-Silane m-(TRIFLUOROMETHYL)PHENYLTRIMETHOXYSILANE BROMOPHENYLTRIMETHOXYSILANE 4-TRIETHOXYSILYLANILINE 3,8,10-Trioxa-9-silatetradecan-14-oic acid, 9-(4-ethoxy-4-oxo-1-phenyl butoxy)-4-oxo-7,9,11-triphenyl-, ethyl ester (P-CHLOROMETHYL)PHENYLTRI-N-PROPOXYSILANE CHLOROPHENYLTRIETHOXYSILANE M-AMINOPHENYLTRIMETHOXYSILANE 4-METHOXYPHENYLTRIMETHOXYSILANE 4-(t-BUTYLDIMETHYLSILOXY)PHENYLTRIMETHOXYSILANE 3,5,8-Trioxa-4-siladecanoic acid, 2,6-bis(2-methoxyphenyl)-4-(2-ethoxy -1-(2-methoxyphenyl)-2-oxoethoxy)-7-oxo-4-phenyl-, ethyl ester PHENYLTRIACETOXYSILANE M-AMINOPHENYLTRIMETHOXYSILANE 3,5,8-Trioxa-4-siladecanoic acid, 2,6-bis(2-chlorophenyl)-4-(1-(2-chlo rophenyl)-2-ethoxy-2-oxoethoxy)-7-oxo-4-phenyl-, ethyl ester M-CHLOROPHENOXYSILATRANE PHENYLTRIS(METHOXYETHOXY)SILANE

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